Synthesis, crystal structure and properties of a manganese(II) complex with an asymmetrical substituted Triaryltriazole

Guo Ping Shen; Jian Zhao; Lang Chen; Feng Sun; Xuan Shen; Dun Ru Zhu; Xiao Qin Liu

Synthesis, crystal structure and properties of a manganese(II) complex with an asymmetrical substituted Triaryltriazole

Guo Ping Shen, Jian Zhao, Lang Chen, Feng Sun, Xuan Shen, Dun Ru Zhu, Xiao Qin Liu

化工学院

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10 引用（Scopus）

摘要

A mononuclear manganese(II) complex, trans-[MnL₂(NCS)₂] (L=3-(p-methoxyphenyl)-4-(p-chlorophenyl) -5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by FTIR, ESI-MS, TG and X-ray crystallography, The complex crystallizes in monoclinic system with space group P2₁/c, a=1.458 5(3) nm, b=0.915 00(18) nm, c = 1.616 3(3) nm, β=101.70(3)°, V=2.112 2(7) nm³, Z=2, and final R₁=0.058 5. The manganese atom lies in a distorted octahedral environment with two NCS ions in the trans positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. The TG analysis shows that the complex is stable below 260 °C. Magnetic data show that the complex is paramagnetic in the range of 1.8~300 K. CCDC: 833359.

源语言	英语
页（从-至）	159-163
页数	5
期刊	Chinese Journal of Inorganic Chemistry
卷	28
期	1
出版状态	已出版 - 1月 2012

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@article{e1d097b5ad1c473b8c05f1405a04451e,

title = "Synthesis, crystal structure and properties of a manganese(II) complex with an asymmetrical substituted Triaryltriazole",

abstract = "A mononuclear manganese(II) complex, trans-[MnL2(NCS)2] (L=3-(p-methoxyphenyl)-4-(p-chlorophenyl) -5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by FTIR, ESI-MS, TG and X-ray crystallography, The complex crystallizes in monoclinic system with space group P21/c, a=1.458 5(3) nm, b=0.915 00(18) nm, c = 1.616 3(3) nm, β=101.70(3)°, V=2.112 2(7) nm3, Z=2, and final R1=0.058 5. The manganese atom lies in a distorted octahedral environment with two NCS ions in the trans positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. The TG analysis shows that the complex is stable below 260 °C. Magnetic data show that the complex is paramagnetic in the range of 1.8~300 K. CCDC: 833359.",

keywords = "1,2,4-triazole, Crystal structure, Mn(II) complex, Properties",

author = "Shen, {Guo Ping} and Jian Zhao and Lang Chen and Feng Sun and Xuan Shen and Zhu, {Dun Ru} and Liu, {Xiao Qin}",

year = "2012",

month = jan,

language = "英语",

volume = "28",

pages = "159--163",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "1",

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TY - JOUR

T1 - Synthesis, crystal structure and properties of a manganese(II) complex with an asymmetrical substituted Triaryltriazole

AU - Shen, Guo Ping

AU - Zhao, Jian

AU - Chen, Lang

AU - Sun, Feng

AU - Shen, Xuan

AU - Zhu, Dun Ru

AU - Liu, Xiao Qin

PY - 2012/1

Y1 - 2012/1

N2 - A mononuclear manganese(II) complex, trans-[MnL2(NCS)2] (L=3-(p-methoxyphenyl)-4-(p-chlorophenyl) -5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by FTIR, ESI-MS, TG and X-ray crystallography, The complex crystallizes in monoclinic system with space group P21/c, a=1.458 5(3) nm, b=0.915 00(18) nm, c = 1.616 3(3) nm, β=101.70(3)°, V=2.112 2(7) nm3, Z=2, and final R1=0.058 5. The manganese atom lies in a distorted octahedral environment with two NCS ions in the trans positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. The TG analysis shows that the complex is stable below 260 °C. Magnetic data show that the complex is paramagnetic in the range of 1.8~300 K. CCDC: 833359.

AB - A mononuclear manganese(II) complex, trans-[MnL2(NCS)2] (L=3-(p-methoxyphenyl)-4-(p-chlorophenyl) -5-(2-pyridyl)-1,2,4-triazole), was synthesized and characterized by FTIR, ESI-MS, TG and X-ray crystallography, The complex crystallizes in monoclinic system with space group P21/c, a=1.458 5(3) nm, b=0.915 00(18) nm, c = 1.616 3(3) nm, β=101.70(3)°, V=2.112 2(7) nm3, Z=2, and final R1=0.058 5. The manganese atom lies in a distorted octahedral environment with two NCS ions in the trans positions. The ligand L coordinates via one triazole nitrogen and one pyridine nitrogen atom. The TG analysis shows that the complex is stable below 260 °C. Magnetic data show that the complex is paramagnetic in the range of 1.8~300 K. CCDC: 833359.

KW - 1,2,4-triazole

KW - Crystal structure

KW - Mn(II) complex

KW - Properties

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M3 - 文章

AN - SCOPUS:84855415658

SN - 1001-4861

VL - 28

SP - 159

EP - 163

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 1

ER -

Synthesis, crystal structure and properties of a manganese(II) complex with an asymmetrical substituted Triaryltriazole

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