Synthesis of aryl allylic fluorides by direct electrophilic fluorination of alkenes

Hai Qing Luo; Teck Peng Loh

doi:10.1016/j.tetlet.2009.01.052

Synthesis of aryl allylic fluorides by direct electrophilic fluorination of alkenes

Hai Qing Luo, Teck Peng Loh

Nanyang Technological University

科研成果: 期刊稿件 › 文章 › 同行评审

22 引用（Scopus）

摘要

Aryl allylic fluorides were synthesized in 47-83% yields by using Selectfluor as the electrophilic reagent in DMF. The outcome of this reaction may be explained by electronic effects while the reactivity was controlled by the stabilization effect of the aryl group on the benzylic cationic intermediates.

源语言	英语
页（从-至）	1554-1556
页数	3
期刊	Tetrahedron Letters
卷	50
期	14
DOI	https://doi.org/10.1016/j.tetlet.2009.01.052
出版状态	已出版 - 8 4月 2009
已对外发布	是

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title = "Synthesis of aryl allylic fluorides by direct electrophilic fluorination of alkenes",

abstract = "Aryl allylic fluorides were synthesized in 47-83% yields by using Selectfluor as the electrophilic reagent in DMF. The outcome of this reaction may be explained by electronic effects while the reactivity was controlled by the stabilization effect of the aryl group on the benzylic cationic intermediates.",

author = "Luo, {Hai Qing} and Loh, {Teck Peng}",

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AU - Luo, Hai Qing

AU - Loh, Teck Peng

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N2 - Aryl allylic fluorides were synthesized in 47-83% yields by using Selectfluor as the electrophilic reagent in DMF. The outcome of this reaction may be explained by electronic effects while the reactivity was controlled by the stabilization effect of the aryl group on the benzylic cationic intermediates.

AB - Aryl allylic fluorides were synthesized in 47-83% yields by using Selectfluor as the electrophilic reagent in DMF. The outcome of this reaction may be explained by electronic effects while the reactivity was controlled by the stabilization effect of the aryl group on the benzylic cationic intermediates.

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DO - 10.1016/j.tetlet.2009.01.052

M3 - 文章

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JO - Tetrahedron Letters

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ER -

Synthesis of aryl allylic fluorides by direct electrophilic fluorination of alkenes

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