Synthesis of cAAC stabilized biradical of "me2Si" and "me2SiCl" monoradical from Me2SiCl2-an important feedstock material

Soumen Sinhababu; Subrata Kundu; Mujahuddin M. Siddiqui; Alexander N. Paesch; Regine Herbst-Irmer; Brigitte Schwederski; Pinaki Saha; Lili Zhao; Gernot Frenking; Wolfgang Kaim; Dietmar Stalke; Herbert W. Roesky

doi:10.1039/c9cc01448a

Synthesis of cAAC stabilized biradical of "me₂Si" and "me₂SiCl" monoradical from Me₂SiCl₂-an important feedstock material

Soumen Sinhababu, Subrata Kundu, Mujahuddin M. Siddiqui, Alexander N. Paesch, Regine Herbst-Irmer, Brigitte Schwederski, Pinaki Saha, Lili Zhao, Gernot Frenking, Wolfgang Kaim, Dietmar Stalke, Herbert W. Roesky

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

9 引用（Scopus）

摘要

The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)₂Me₂Si (1), (cAAC = C(CH₂)(CMe₂)₂N-2,6-i-Pr₂C₆H₃), synthesized from the reduction of Me₂SiCl₂ using two equivalents of KC₈ in the presence of two equivalents of cAAC. The reduction of Me₂SiCl₂ by one equivalent of KC₈ in the presence of one equivalent of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me₂SiCl (2).

源语言	英语
页（从-至）	4534-4537
页数	4
期刊	Chemical Communications
卷	55
期	31
DOI	https://doi.org/10.1039/c9cc01448a
出版状态	已出版 - 2019

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10.1039/c9cc01448a

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Sinhababu, S., Kundu, S., Siddiqui, M. M., Paesch, A. N., Herbst-Irmer, R., Schwederski, B., Saha, P., Zhao, L., Frenking, G., Kaim, W., Stalke, D., & Roesky, H. W. (2019). Synthesis of cAAC stabilized biradical of "me₂Si" and "me₂SiCl" monoradical from Me₂SiCl₂-an important feedstock material. Chemical Communications, 55(31), 4534-4537. https://doi.org/10.1039/c9cc01448a

@article{67eda7e2a7d24a5da44b094ddb05c48e,

title = "Synthesis of cAAC stabilized biradical of {"}me2Si{"} and {"}me2SiCl{"} monoradical from Me2SiCl2-an important feedstock material",

abstract = "The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)2Me2Si (1), (cAAC = C(CH2)(CMe2)2N-2,6-i-Pr2C6H3), synthesized from the reduction of Me2SiCl2 using two equivalents of KC8 in the presence of two equivalents of cAAC. The reduction of Me2SiCl2 by one equivalent of KC8 in the presence of one equivalent of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2).",

author = "Soumen Sinhababu and Subrata Kundu and Siddiqui, {Mujahuddin M.} and Paesch, {Alexander N.} and Regine Herbst-Irmer and Brigitte Schwederski and Pinaki Saha and Lili Zhao and Gernot Frenking and Wolfgang Kaim and Dietmar Stalke and Roesky, {Herbert W.}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc01448a",

language = "英语",

volume = "55",

pages = "4534--4537",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "31",

}

Sinhababu, S, Kundu, S, Siddiqui, MM, Paesch, AN, Herbst-Irmer, R, Schwederski, B, Saha, P, Zhao, L , Frenking, G, Kaim, W, Stalke, D & Roesky, HW 2019, 'Synthesis of cAAC stabilized biradical of "me₂Si" and "me₂SiCl" monoradical from Me₂SiCl₂-an important feedstock material', Chemical Communications, 卷 55, 号码 31, 页码 4534-4537. https://doi.org/10.1039/c9cc01448a

TY - JOUR

T1 - Synthesis of cAAC stabilized biradical of "me2Si" and "me2SiCl" monoradical from Me2SiCl2-an important feedstock material

AU - Sinhababu, Soumen

AU - Kundu, Subrata

AU - Siddiqui, Mujahuddin M.

AU - Paesch, Alexander N.

AU - Herbst-Irmer, Regine

AU - Schwederski, Brigitte

AU - Saha, Pinaki

AU - Zhao, Lili

AU - Frenking, Gernot

AU - Kaim, Wolfgang

AU - Stalke, Dietmar

AU - Roesky, Herbert W.

PY - 2019

Y1 - 2019

N2 - The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)2Me2Si (1), (cAAC = C(CH2)(CMe2)2N-2,6-i-Pr2C6H3), synthesized from the reduction of Me2SiCl2 using two equivalents of KC8 in the presence of two equivalents of cAAC. The reduction of Me2SiCl2 by one equivalent of KC8 in the presence of one equivalent of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2).

AB - The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)2Me2Si (1), (cAAC = C(CH2)(CMe2)2N-2,6-i-Pr2C6H3), synthesized from the reduction of Me2SiCl2 using two equivalents of KC8 in the presence of two equivalents of cAAC. The reduction of Me2SiCl2 by one equivalent of KC8 in the presence of one equivalent of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2).

UR - http://www.scopus.com/inward/record.url?scp=85064256935&partnerID=8YFLogxK

U2 - 10.1039/c9cc01448a

DO - 10.1039/c9cc01448a

M3 - 文章

C2 - 30924826

AN - SCOPUS:85064256935

SN - 1359-7345

VL - 55

SP - 4534

EP - 4537

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Synthesis of cAAC stabilized biradical of "me2Si" and "me2SiCl" monoradical from Me2SiCl2-an important feedstock material

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Synthesis of cAAC stabilized biradical of "me₂Si" and "me₂SiCl" monoradical from Me₂SiCl₂-an important feedstock material