Synthesis of Polyaromatic Rings: Rh(III)-Catalyzed [5 + 1] Annulation of Enaminones with Vinyl Esters through C-H Bond Functionalization

Gaohui Liang, Jiaxin Rong, Wangbin Sun, Gengjia Chen, Yaojia Jiang, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

66 引用 (Scopus)

摘要

An expedient [5 + 1] annulation method via Rh(III)-catalyzed C-H bond functionalization of enaminones to synthesize polyaromatic rings is described. The reaction tolerates a broad range of functional groups and offers a new entry to construct polycyclic aromatic compounds with amino and formyl substituents. A possible reaction mechanism was proposed based on the results obtained from isotope labeling experiments.

源语言英语
页(从-至)7326-7331
页数6
期刊Organic Letters
20
22
DOI
出版状态已出版 - 16 11月 2018

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