Synthesis, spectroscopic characterization and X-ray crystal structure of vanadylpolymolybdophosphates with monocapped Keggin polyanion [PMo5V7O40(VO)]7-

Chuan Jiang Hu, Chun Ying Duan, Yong Jiang Liu, Chang Sheng Lu, Xiao Ming Ren, Qing Jin Meng

科研成果: 期刊稿件文章同行评审

8 引用 (Scopus)

摘要

The preparation of the heteropolyoxometalates K6[HPMo5V7O40(VO)]·16H 2O (1); (n-Bu4N)4[H3PMo5V7O 40(VO)] (2) and (CN3H6)6[HPMo5V7O 40(VO)]·4H2O (3) is described. Compounds 2 and 3 have been characterized by X-ray diffraction methods. Both compounds contain a monocapped Keggin anion. For compound 2 the capping V=O group is disordered in six sites, while there are two types of sites for the capping V=O group for compound 3. The IR spectra have been investigated.

源语言英语
页(从-至)2117-2121
页数5
期刊Polyhedron
20
17
DOI
出版状态已出版 - 15 7月 2001
已对外发布

指纹

探究 'Synthesis, spectroscopic characterization and X-ray crystal structure of vanadylpolymolybdophosphates with monocapped Keggin polyanion [PMo5V7O40(VO)]7-' 的科研主题。它们共同构成独一无二的指纹。

引用此