tert-Butyl Nitrite as a Twofold Hydrogen Abstractor for Dehydrogenative Coupling of Aldehydes with N-Hydroxyimides

Peng Fei Dai; Yi Ping Wang; Jian Ping Qu; Yan Biao Kang

doi:10.1021/acs.orglett.1c03434

tert-Butyl Nitrite as a Twofold Hydrogen Abstractor for Dehydrogenative Coupling of Aldehydes with N-Hydroxyimides

Peng Fei Dai, Yi Ping Wang, Jian Ping Qu, Yan Biao Kang

化学与分子工程学院

科研成果: 期刊稿件 › 文章 › 同行评审

15 引用（Scopus）

摘要

A synthetically practical transition metal/catalyst/halogen-free dehydrogenative coupling of aldehydes with N-hydroxyimides promoted solely by tert-butyl nitrite under mild conditions was developed. tert-Butyl nitrite generates two radicals (^tBuO and NO) and thus works as a twofold hydrogen abstractor. A diverse array of N-hydroxyimide esters were prepared from either aliphatic or aromatic aldehydes. Benzoyl-substituted aldehydes such as 2-oxo-2-phenylacetaldehyde are also suitable.

源语言	英语
页（从-至）	9360-9364
页数	5
期刊	Organic Letters
卷	23
期	24
DOI	https://doi.org/10.1021/acs.orglett.1c03434
出版状态	已出版 - 17 12月 2021

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author = "Dai, {Peng Fei} and Wang, {Yi Ping} and Qu, {Jian Ping} and Kang, {Yan Biao}",

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AU - Dai, Peng Fei

AU - Wang, Yi Ping

AU - Qu, Jian Ping

AU - Kang, Yan Biao

PY - 2021/12/17

Y1 - 2021/12/17

N2 - A synthetically practical transition metal/catalyst/halogen-free dehydrogenative coupling of aldehydes with N-hydroxyimides promoted solely by tert-butyl nitrite under mild conditions was developed. tert-Butyl nitrite generates two radicals (tBuO and NO) and thus works as a twofold hydrogen abstractor. A diverse array of N-hydroxyimide esters were prepared from either aliphatic or aromatic aldehydes. Benzoyl-substituted aldehydes such as 2-oxo-2-phenylacetaldehyde are also suitable.

AB - A synthetically practical transition metal/catalyst/halogen-free dehydrogenative coupling of aldehydes with N-hydroxyimides promoted solely by tert-butyl nitrite under mild conditions was developed. tert-Butyl nitrite generates two radicals (tBuO and NO) and thus works as a twofold hydrogen abstractor. A diverse array of N-hydroxyimide esters were prepared from either aliphatic or aromatic aldehydes. Benzoyl-substituted aldehydes such as 2-oxo-2-phenylacetaldehyde are also suitable.

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JF - Organic Letters

IS - 24

ER -

tert-Butyl Nitrite as a Twofold Hydrogen Abstractor for Dehydrogenative Coupling of Aldehydes with N-Hydroxyimides

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