@article{cdfa0e7d47e7443ea0028aa205fe87cf,
title = "The effect of H2O2 desorption on achieving improved selectivity for direct synthesis of H2O2 over TiO2(B)/anatase supported Pd catalyst",
abstract = "The effect of H2O2 desorption on the direct synthesis of H2O2 from H2 and O2 over Pd-TiO2(B)/anatase and Pd-anatase has been investigated. The interaction between H2O2 and the support has been studied by isothermal microcalorimetry and molecular dynamics (MD) simulation. H2O2 desorption from TiO2(B)/anatase is more facile due to the existence of TiO2(B). The accelerated H2O2 desorption from the catalyst surface can effectively decrease the hydrogenation rate of H2O2 over Pd-TiO2(B)/anatase, which results in a 57% increase in the selectivity of H2O2 synthesis.",
keywords = "Direct synthesis of HO, HO desorption, Isothermal microcalorimetry, Molecular dynamics simulation, Pd-TiO(B)/anatase, Selectivity",
author = "Rui Tu and Shuying Chen and Wei Cao and Suoying Zhang and Licheng Li and Tuo Ji and Jiahua Zhu and Jun Li and Xiaohua Lu",
note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",
year = "2017",
month = jan,
day = "10",
doi = "10.1016/j.catcom.2016.10.024",
language = "英语",
volume = "89",
pages = "69--72",
journal = "Catalysis Communications",
issn = "1566-7367",
publisher = "Elsevier B.V.",
}