@article{0c6e8f7d8d704c2f83fb5dcf2449b95b,
title = "The first In(OTf)3-catalyzed conversion of kinetically formed homoallylic alcohols into the thermodynamically preferred regioisomers: Application to the synthesis of 22α-sterols",
abstract = "A retro-ene reaction that generates the parent aldehyde and a sigmatropic rearrangement are involved in the In(OTf)3-catalyzed conversion of homoallylic alcohols 1 into the thermodynamically favored regioisomers 2. This method can be used for the stereocontrolled synthesis of linear homoallylic 22α-sterols from their readily accessible branched 22β isomers.",
keywords = "Ene reaction, Indium, Retro reactions, Sigmatropic rearrangement",
author = "Loh, {Teck Peng} and Tan, {Kui Thong} and Hu, {Qi Ying}",
year = "2001",
month = aug,
day = "3",
doi = "10.1002/1521-3773(20010803)40:15<2921::AID-ANIE2921>3.0.CO;2-V",
language = "英语",
volume = "40",
pages = "2921--2922",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "15",
}