TY - JOUR
T1 - Two octamolybdate-based complexes
T2 - Hydrothermal synthesis, structural characterization and properties
AU - Xu, Xiao
AU - Ju, Weiwei
AU - Hou, Wentao
AU - Zhu, Dunru
AU - Xu, Yan
PY - 2014/1/7
Y1 - 2014/1/7
N2 - Two octamolybdate-based inorganic-organic hybrid complexes constructed from rigid mmt ligand and flexible ttmb ligand respectively (mmt = 5-mercapto-1-methyltetrazole, ttmb = 1,3,5-tri(1,2,4-triazol-1-ylmethyl)-2,4,6- trimethylbenzene), namely, [Ag8(H2O)2(mmt) 4(β-Mo8O26)] (1), Ag4(ttmb) 2(β-Mo8O26) (2), have been successfully synthesized. Crystal structural analysis reveals that compound 1 is built up of [β-Mo8O26]4- clusters covalently linked by Ag-mmt metal organic layers, which possess interesting hexa-nuclear Ag clusters. In compound 2, the wave-like Ag-ttmb layers are linked by 1D Ag-[β-Mo8O26]4- chains to form a 3D framework. The electrochemical behavior of 1-2 and the luminescent property of 2 were investigated.
AB - Two octamolybdate-based inorganic-organic hybrid complexes constructed from rigid mmt ligand and flexible ttmb ligand respectively (mmt = 5-mercapto-1-methyltetrazole, ttmb = 1,3,5-tri(1,2,4-triazol-1-ylmethyl)-2,4,6- trimethylbenzene), namely, [Ag8(H2O)2(mmt) 4(β-Mo8O26)] (1), Ag4(ttmb) 2(β-Mo8O26) (2), have been successfully synthesized. Crystal structural analysis reveals that compound 1 is built up of [β-Mo8O26]4- clusters covalently linked by Ag-mmt metal organic layers, which possess interesting hexa-nuclear Ag clusters. In compound 2, the wave-like Ag-ttmb layers are linked by 1D Ag-[β-Mo8O26]4- chains to form a 3D framework. The electrochemical behavior of 1-2 and the luminescent property of 2 were investigated.
UR - http://www.scopus.com/inward/record.url?scp=84888405307&partnerID=8YFLogxK
U2 - 10.1039/c3ce41706a
DO - 10.1039/c3ce41706a
M3 - 文章
AN - SCOPUS:84888405307
SN - 1466-8033
VL - 16
SP - 82
EP - 88
JO - CrystEngComm
JF - CrystEngComm
IS - 1
ER -