Using ultrasonic (US)-initiated template copolymerization for preparation of an enhanced cationic polyacrylamide (CPAM) and its application in sludge dewatering

In this study, the ultrasonic (US)-initiated template copolymerization was employed to synthesize a novel cationic polyacrylamide (CPAM) characterized by a microblock structure using dimethyldiallylammonium chloride (DMDAAC) and acrylamide (AM) as monomers, and sodium polyacrylate (NaPAA) as template. The polymers structure property was analyzed by Fourier transform infrared spectroscopy (FT-IR), ¹H nuclear magnetic resonance spectroscopy (¹H NMR) and thermogravimetric analysis (TGA). The results showed that a novel cationic microblock structure was successfully synthesized in the template copolymer of DMDAAC and AM (TPADM). Meanwhile, the analysis result of association constant (M_K) provided powerful support for a I Zip-up (ZIP) template polymerization mechanism and the formation of the microblock structure. The factors affecting the polymerization were investigated, including ultrasonic power, ultrasonic time, monomer concentration, initiator concentration, m_AM:m_DMDAAC and n_NaPAA:n_DMDAAC. The sludge dewatering performance of the polymers was evaluated in terms of specific resistance to filtration (SRF), filter cake moisture content (FCMC), floc size (d₅₀) and fractal dimension (D_f). Flocculation mechanism was also analyzed and discussed. The sludge dewatering results revealed that the polymer with the novel microblock structure showed a more excellent flocculation performance than those with randomly distributed cationic units. A desirable flocculation performance with a SRF of 4.5 × 10¹² m kg⁻¹, FCMC of 73.1%, d₅₀ of 439.156 µm and D_f of 1.490 were obtained at pH of 7.0, dosage of 40 mg L⁻¹ and the molecular weight of 5.0 × 10⁶ Da. The cationic microblock extremely enhanced the polymer charge neutralization and bridging ability, thus obtaining the excellent sludge dewatering performance.