Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

Chao Shi; Huibin Sun; Xiao Tang; Wen Lv; Hong Yan; Qiang Zhao; Jingxia Wang; Wei Huang

doi:10.1002/anie.201307333

Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

Chao Shi, Huibin Sun, Xiao Tang, Wen Lv, Hong Yan, Qiang Zhao, Jingxia Wang, Wei Huang

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195 引用（Scopus）

摘要

Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

源语言	英语
页（从-至）	13434-13438
页数	5
期刊	Angewandte Chemie - International Edition
卷	52
期	50
DOI	https://doi.org/10.1002/anie.201307333
出版状态	已出版 - 9 12月 2013
已对外发布	是

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abstract = "Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.",

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T1 - Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

AU - Shi, Chao

AU - Sun, Huibin

AU - Tang, Xiao

AU - Lv, Wen

AU - Yan, Hong

AU - Zhao, Qiang

AU - Wang, Jingxia

AU - Huang, Wei

PY - 2013/12/9

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N2 - Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

AB - Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

KW - bioimaging

KW - carboranes

KW - iridium

KW - phosphorescence

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Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

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