Visible Light-Mediated Trifluoromethylation of Fluorinated Alkenes via C−F Bond Cleavage

Liu Hai Wu, Jun Kee Cheng, Liang Shen, Zhi Liang Shen, Teck Peng Loh

科研成果: 期刊稿件文章同行评审

100 引用 (Scopus)

摘要

A convenient photoredox-catalyzed defluorinative trifluoromethylation of α-trifluoromethyl alkenes and gem-difluoroalkenes is developed. The reactions proceeded efficiently via trifluoromethyl radical addition followed by β-fluorine elimination process, providing a new entry to multifluorinated alkenes in moderate to good yields with excellent stereoselectivity. (Figure presented.).

源语言英语
页(从-至)3894-3899
页数6
期刊Advanced Synthesis and Catalysis
360
20
DOI
出版状态已出版 - 18 10月 2018

指纹

探究 'Visible Light-Mediated Trifluoromethylation of Fluorinated Alkenes via C−F Bond Cleavage' 的科研主题。它们共同构成独一无二的指纹。

引用此