[(η5-C5Me5)Al-Fe(CO)4] - Synthesis, structure, and bonding

J. Weiss; D. Stetzkamp; B. Nuber; R. A. Fischer; C. Boehme; G. Frenking

[(η⁵-C₅Me₅)Al-Fe(CO)₄] - Synthesis, structure, and bonding

J. Weiss, D. Stetzkamp, B. Nuber, R. A. Fischer, C. Boehme, G. Frenking

Heidelberg University

Research output: Contribution to journal › Article › peer-review

93 Scopus citations

Abstract

The bonding in the unprecedented complex [Cp*Al-Fe(CO)₄] was investigated by quantum theoretical methods by using the model compound [CpAl-Fe(CO)₄]. The strength of Al → Fe donor-acceptor bond, which is characteristic for this complex, is estimated to be about 50 kcal mol^-1.

Original language	English
Pages (from-to)	70-72
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	36
Issue number	1-2
State	Published - 1997
Externally published	Yes

Keywords

aluminum
complex chemistry
density functional calculations
iron
structure elucidation

Cite this

Weiss, J., Stetzkamp, D., Nuber, B., Fischer, R. A., Boehme, C., & Frenking, G. (1997). [(η⁵-C₅Me₅)Al-Fe(CO)₄] - Synthesis, structure, and bonding. Angewandte Chemie - International Edition, 36(1-2), 70-72.

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AU - Weiss, J.

AU - Stetzkamp, D.

AU - Nuber, B.

AU - Fischer, R. A.

AU - Boehme, C.

AU - Frenking, G.

PY - 1997

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AB - The bonding in the unprecedented complex [Cp*Al-Fe(CO)4] was investigated by quantum theoretical methods by using the model compound [CpAl-Fe(CO)4]. The strength of Al → Fe donor-acceptor bond, which is characteristic for this complex, is estimated to be about 50 kcal mol-1.

KW - aluminum

KW - complex chemistry

KW - density functional calculations

KW - iron

KW - structure elucidation

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ER -

[(η5-C5Me5)Al-Fe(CO)4] - Synthesis, structure, and bonding

Abstract

Keywords

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[(η⁵-C₅Me₅)Al-Fe(CO)₄] - Synthesis, structure, and bonding