[(η5-C5Me5)Al-Fe(CO)4] Synthesis, Structure, and Bonding

Jurij Weiss; Dana Stetzkamp; Bernhard Nuber; Roland A. Fischer; Christian Boehme; Gernot Frenking

doi:10.1002/anie.199700701

[(η⁵-C₅Me₅)Al-Fe(CO)₄] Synthesis, Structure, and Bonding

Jurij Weiss, Dana Stetzkamp, Bernhard Nuber, Roland A. Fischer, Christian Boehme, Gernot Frenking

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

The bonding in the unprecedented complex [Cp*Al-Fe(CO)₄] was investigated by quantum theoretical methods by using the model compound [CpAl-Fe(CO)₄]. The strength of Al → Fe donor-acceptor bond, which is characteristic for this complex, is estimated to be about 50 kcal mol^-1.

Original language	English
Pages (from-to)	70-72
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	36
Issue number	1-2
DOIs	https://doi.org/10.1002/anie.199700701
State	Published - 1997
Externally published	Yes

Keywords

Aluminum
Complex chemistry
Density functional calculations
Iron
Structure elucidation

Access to Document

10.1002/anie.199700701

Cite this

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abstract = "The bonding in the unprecedented complex [Cp*Al-Fe(CO)4] was investigated by quantum theoretical methods by using the model compound [CpAl-Fe(CO)4]. The strength of Al → Fe donor-acceptor bond, which is characteristic for this complex, is estimated to be about 50 kcal mol-1.",

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AU - Stetzkamp, Dana

AU - Nuber, Bernhard

AU - Fischer, Roland A.

AU - Boehme, Christian

AU - Frenking, Gernot

PY - 1997

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AB - The bonding in the unprecedented complex [Cp*Al-Fe(CO)4] was investigated by quantum theoretical methods by using the model compound [CpAl-Fe(CO)4]. The strength of Al → Fe donor-acceptor bond, which is characteristic for this complex, is estimated to be about 50 kcal mol-1.

KW - Aluminum

KW - Complex chemistry

KW - Density functional calculations

KW - Iron

KW - Structure elucidation

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M3 - 文章

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