2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

Lei Gong; Christian Müller; Mehmet Ali Celik; Gernot Frenking; Eric Meggers

doi:10.1039/c0nj00787k

2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

Lei Gong, Christian Müller, Mehmet Ali Celik, Gernot Frenking, Eric Meggers

University of Marburg

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η⁶-C₆H₆)Cl₂] ₂.

Original language	English
Pages (from-to)	788-793
Number of pages	6
Journal	New Journal of Chemistry
Volume	35
Issue number	4
DOIs	https://doi.org/10.1039/c0nj00787k
State	Published - Apr 2011
Externally published	Yes

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title = "2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry",

abstract = "In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η6-C6H6)Cl2] 2.",

author = "Lei Gong and Christian M{\"u}ller and Celik, {Mehmet Ali} and Gernot Frenking and Eric Meggers",

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T1 - 2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

AU - Gong, Lei

AU - Müller, Christian

AU - Celik, Mehmet Ali

AU - Frenking, Gernot

AU - Meggers, Eric

PY - 2011/4

Y1 - 2011/4

N2 - In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η6-C6H6)Cl2] 2.

AB - In this study, the bidentate ligand (R)-2-diphenylphosphino-2′- hydroxy-1,1′-binaphthyl (HO-MOP) was investigated as a chiral auxiliary for the asymmetric synthesis of ruthenium polypyridyl complexes. It was found that (R)-HO-MOP serves as an effective chiral auxiliary starting from different precursor complexes, most notably using the commercially available half-sandwich complex [Ru(η6-C6H6)Cl2] 2.

UR - http://www.scopus.com/inward/record.url?scp=79953253508&partnerID=8YFLogxK

U2 - 10.1039/c0nj00787k

DO - 10.1039/c0nj00787k

M3 - 文章

AN - SCOPUS:79953253508

SN - 1144-0546

VL - 35

SP - 788

EP - 793

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 4

ER -

2-Diphenylphosphino-2′-hydroxy-1,1′-binaphthyl as a chiral auxiliary for asymmetric coordination chemistry

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