A 2-fold interpenetrated framework based on tetranuclear heterometallic cluster: Synthesis, structure and magnetic properties

Guang Xiang Liu; Heng Xu; Xiao Ming Ren

doi:10.1002/zaac.200700537

A 2-fold interpenetrated framework based on tetranuclear heterometallic cluster: Synthesis, structure and magnetic properties

Guang Xiang Liu, Heng Xu, Xiao Ming Ren

Anqing Normal University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A 2-fold parallel interpenetrated polymer, ZnCo(OH)(pheno)(p-BDC) _1.5·H₂O (1) (pheno = phenanthrene-9,10-dione; p-BDC = 1,4-benzenedicarboxylate) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, ICP and single crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected α-Po network. The magnetic behavior for 1 was studied in the temperature range of 1.8-300 K.

Original language	English
Pages (from-to)	927-930
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	634
Issue number	5
DOIs	https://doi.org/10.1002/zaac.200700537
State	Published - May 2008
Externally published	Yes

Keywords

Carboxylate ligand
Heterometallic complex
Magnetic property
α-Po

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10.1002/zaac.200700537

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title = "A 2-fold interpenetrated framework based on tetranuclear heterometallic cluster: Synthesis, structure and magnetic properties",

abstract = "A 2-fold parallel interpenetrated polymer, ZnCo(OH)(pheno)(p-BDC) 1.5·H2O (1) (pheno = phenanthrene-9,10-dione; p-BDC = 1,4-benzenedicarboxylate) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, ICP and single crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected α-Po network. The magnetic behavior for 1 was studied in the temperature range of 1.8-300 K.",

keywords = "Carboxylate ligand, Heterometallic complex, Magnetic property, α-Po",

author = "Liu, {Guang Xiang} and Heng Xu and Ren, {Xiao Ming}",

year = "2008",

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doi = "10.1002/zaac.200700537",

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volume = "634",

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T1 - A 2-fold interpenetrated framework based on tetranuclear heterometallic cluster

T2 - Synthesis, structure and magnetic properties

AU - Liu, Guang Xiang

AU - Xu, Heng

AU - Ren, Xiao Ming

PY - 2008/5

Y1 - 2008/5

N2 - A 2-fold parallel interpenetrated polymer, ZnCo(OH)(pheno)(p-BDC) 1.5·H2O (1) (pheno = phenanthrene-9,10-dione; p-BDC = 1,4-benzenedicarboxylate) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, ICP and single crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected α-Po network. The magnetic behavior for 1 was studied in the temperature range of 1.8-300 K.

AB - A 2-fold parallel interpenetrated polymer, ZnCo(OH)(pheno)(p-BDC) 1.5·H2O (1) (pheno = phenanthrene-9,10-dione; p-BDC = 1,4-benzenedicarboxylate) has been prepared by hydrothermal synthesis and structurally characterized by IR, elemental analysis, ICP and single crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected α-Po network. The magnetic behavior for 1 was studied in the temperature range of 1.8-300 K.

KW - Carboxylate ligand

KW - Heterometallic complex

KW - Magnetic property

KW - α-Po

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DO - 10.1002/zaac.200700537

M3 - 文章

AN - SCOPUS:53849135198

SN - 0044-2313

VL - 634

SP - 927

EP - 930

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 5

ER -

A 2-fold interpenetrated framework based on tetranuclear heterometallic cluster: Synthesis, structure and magnetic properties

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Keywords

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