TY - JOUR
T1 - A 2D Cu(I) triazolate coordination polymer
T2 - Synthesis and characterization of [Cu4Br4(C8H8N4)2]·H2O
AU - Liu, Yu
AU - Zhao, Zhen Guo
AU - Fang, Zhen Lan
AU - Yu, Rong Min
AU - Lu, Can Zhong
PY - 2009/7
Y1 - 2009/7
N2 - The title compound, [Cu4Br4L2]·H2O (1), (L = C8H8N4, 4-(4-aminophenyl)-4H-1,2,4-triazole) was synthesized from a hydrothermal reaction and characterized by single-crystal X-ray diffraction analysis, IR, and fluorescent spectroscopy. The structure of 1 shows a two-dimensional rectangular grid layer, which is formed by the interconnection of Cu4Br4 step-like and the tris(monodentate) L bridges, with guest water molecules filling in the grid. Compound 1 in the solid state exhibits deep green emission with maximum at 538 nm.
AB - The title compound, [Cu4Br4L2]·H2O (1), (L = C8H8N4, 4-(4-aminophenyl)-4H-1,2,4-triazole) was synthesized from a hydrothermal reaction and characterized by single-crystal X-ray diffraction analysis, IR, and fluorescent spectroscopy. The structure of 1 shows a two-dimensional rectangular grid layer, which is formed by the interconnection of Cu4Br4 step-like and the tris(monodentate) L bridges, with guest water molecules filling in the grid. Compound 1 in the solid state exhibits deep green emission with maximum at 538 nm.
KW - 4-(4-Aminophenyl)-4H-1,2,4-triazole
KW - Coordination polymer
KW - Copper(I) bromine
KW - Photoluminescent
UR - http://www.scopus.com/inward/record.url?scp=67649359325&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2009.04.030
DO - 10.1016/j.inoche.2009.04.030
M3 - 文章
AN - SCOPUS:67649359325
SN - 1387-7003
VL - 12
SP - 599
EP - 601
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 7
ER -