Abstract
A facile method has been developed to incorporate FeOx into the channels of anionic surfactant-templated mesoporous silica (AMS). This synthesized method was based on a novel templating route (S−[MN]+I−), in which Sar-Na (N-Lauroylsarcosine sodium) was employed as structure-directing agent (S−), Fe ion functionalized APATES (N-[3-(Trimethoxysilyl)propyl]ethylenediamine) as co-structure directing agent ([MN]+). The Fe ion functionalized APATES (Fe[APATES]+) could establish a critical interaction between the surfactant head group and silica species by counterion-mediated interaction during the synthesis process. The synthesized samples were characterized with XRD, N2 adsorption, XPS, FT-IR, UV-vis, H2-TPR, TEM. The results revealed that FeOx species could be highly dispersed onto the pore channel surface and have a strong interaction with the silica wall. Furthermore, this catalyst of FeOx-AMS exhibited high catalytic performances for the hydroxylation of phenol.
Original language | English |
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Pages (from-to) | 1305-1313 |
Number of pages | 9 |
Journal | ChemistrySelect |
Volume | 1 |
Issue number | 7 |
DOIs | |
State | Published - 16 May 2016 |
Keywords
- AMS
- FeO phenol
- Metallization-organosilicon
- highly-dispersed