A highly porous: Rht -type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities

Baishu Zheng, Hang Wang, Zhaoxu Wang, Noriaki Ozaki, Cheng Hang, Xin Luo, Lu Huang, Wenjiang Zeng, Ming Yang, Jingui Duan

Research output: Contribution to journalArticlepeer-review

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Abstract

A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2 g-1, and a large CO2 uptake capability (38.9 mmol g-1 under 36 bar) with an excellent selectivity of CO2/CH4 (7.3) and CO2/N2 (32.5) at 273 K.

Original languageEnglish
Pages (from-to)12988-12991
Number of pages4
JournalChemical Communications
Volume52
Issue number88
DOIs
StatePublished - 2016

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