A highly porous: Rht -type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities

Baishu Zheng; Hang Wang; Zhaoxu Wang; Noriaki Ozaki; Cheng Hang; Xin Luo; Lu Huang; Wenjiang Zeng; Ming Yang; Jingui Duan

doi:10.1039/c6cc06734d

A highly porous: Rht -type acylamide-functionalized metal-organic framework exhibiting large CO₂ uptake capabilities

Baishu Zheng, Hang Wang, Zhaoxu Wang, Noriaki Ozaki, Cheng Hang, Xin Luo, Lu Huang, Wenjiang Zeng, Ming Yang, Jingui Duan

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m² g^-1, and a large CO₂ uptake capability (38.9 mmol g^-1 under 36 bar) with an excellent selectivity of CO₂/CH₄ (7.3) and CO₂/N₂ (32.5) at 273 K.

Original language	English
Pages (from-to)	12988-12991
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	88
DOIs	https://doi.org/10.1039/c6cc06734d
State	Published - 2016

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title = "A highly porous: Rht -type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities",

abstract = "A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2 g-1, and a large CO2 uptake capability (38.9 mmol g-1 under 36 bar) with an excellent selectivity of CO2/CH4 (7.3) and CO2/N2 (32.5) at 273 K.",

author = "Baishu Zheng and Hang Wang and Zhaoxu Wang and Noriaki Ozaki and Cheng Hang and Xin Luo and Lu Huang and Wenjiang Zeng and Ming Yang and Jingui Duan",

note = "Publisher Copyright: {\textcopyright} The 2016 Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc06734d",

language = "英语",

volume = "52",

pages = "12988--12991",

journal = "Chemical Communications",

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TY - JOUR

T1 - A highly porous

T2 - Rht -type acylamide-functionalized metal-organic framework exhibiting large CO2 uptake capabilities

AU - Zheng, Baishu

AU - Wang, Hang

AU - Wang, Zhaoxu

AU - Ozaki, Noriaki

AU - Hang, Cheng

AU - Luo, Xin

AU - Huang, Lu

AU - Zeng, Wenjiang

AU - Yang, Ming

AU - Duan, Jingui

PY - 2016

Y1 - 2016

N2 - A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2 g-1, and a large CO2 uptake capability (38.9 mmol g-1 under 36 bar) with an excellent selectivity of CO2/CH4 (7.3) and CO2/N2 (32.5) at 273 K.

AB - A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2 g-1, and a large CO2 uptake capability (38.9 mmol g-1 under 36 bar) with an excellent selectivity of CO2/CH4 (7.3) and CO2/N2 (32.5) at 273 K.

UR - http://www.scopus.com/inward/record.url?scp=84993990027&partnerID=8YFLogxK

U2 - 10.1039/c6cc06734d

DO - 10.1039/c6cc06734d

M3 - 文章

AN - SCOPUS:84993990027

SN - 1359-7345

VL - 52

SP - 12988

EP - 12991

JO - Chemical Communications

JF - Chemical Communications

IS - 88

ER -

A highly porous: Rht -type acylamide-functionalized metal-organic framework exhibiting large CO₂ uptake capabilities

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