Abstract
A new, highly porous acylamide-functionalized MOF with a (3,24)-connected rht-type network (HNUST-5) has been synthesized and structurally determined using powder X-ray diffraction. HNUST-5 exhibits a high BET surface area of 3643 m2 g-1, and a large CO2 uptake capability (38.9 mmol g-1 under 36 bar) with an excellent selectivity of CO2/CH4 (7.3) and CO2/N2 (32.5) at 273 K.
Original language | English |
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Pages (from-to) | 12988-12991 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 52 |
Issue number | 88 |
DOIs | |
State | Published - 2016 |