A new "fully reduced" polyoxovanadate constructed from nanosized triangle-shaped [VIII3VIV18P 6O60(DACH)3]}9- cluster anions exhibiting ferrimagnetic interactions

Cong Ling Wang, Zhi Bin Zhang, Jie Fu, Yan Xu, Dun Ru Zhu

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

Magnetic personality: A pentavalent vanadium source was employed to prepare the largest highly reduced polyoxovanadate cluster by virtue of the reducing power of 1,2-diaminocyclohexane under hydrothermal conditions. The new non-classical triangle-shaped cluster shows good catalytic selectivity for the oxidation of styrene and exhibits ferrimagnetic interactions that could make it a promising magnetic material.

Original languageEnglish
Pages (from-to)11909-11912
Number of pages4
JournalChemistry - A European Journal
Volume18
Issue number38
DOIs
StatePublished - 17 Sep 2012

Keywords

  • X-ray diffraction
  • catalysis
  • hydrothermal synthesis
  • polyoxometalates
  • vanadates

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