A new "fully reduced" polyoxovanadate constructed from nanosized triangle-shaped [VIII3VIV18P 6O60(DACH)3]}9- cluster anions exhibiting ferrimagnetic interactions

Cong Ling Wang; Zhi Bin Zhang; Jie Fu; Yan Xu; Dun Ru Zhu

doi:10.1002/chem.201200261

A new "fully reduced" polyoxovanadate constructed from nanosized triangle-shaped [V^III₃V^IV₁₈P ₆O₆₀(DACH)₃]}^9- cluster anions exhibiting ferrimagnetic interactions

Cong Ling Wang, Zhi Bin Zhang, Jie Fu, Yan Xu, Dun Ru Zhu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Magnetic personality: A pentavalent vanadium source was employed to prepare the largest highly reduced polyoxovanadate cluster by virtue of the reducing power of 1,2-diaminocyclohexane under hydrothermal conditions. The new non-classical triangle-shaped cluster shows good catalytic selectivity for the oxidation of styrene and exhibits ferrimagnetic interactions that could make it a promising magnetic material.

Original language	English
Pages (from-to)	11909-11912
Number of pages	4
Journal	Chemistry - A European Journal
Volume	18
Issue number	38
DOIs	https://doi.org/10.1002/chem.201200261
State	Published - 17 Sep 2012

Keywords

X-ray diffraction
catalysis
hydrothermal synthesis
polyoxometalates
vanadates

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10.1002/chem.201200261

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abstract = "Magnetic personality: A pentavalent vanadium source was employed to prepare the largest highly reduced polyoxovanadate cluster by virtue of the reducing power of 1,2-diaminocyclohexane under hydrothermal conditions. The new non-classical triangle-shaped cluster shows good catalytic selectivity for the oxidation of styrene and exhibits ferrimagnetic interactions that could make it a promising magnetic material.",

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AU - Zhang, Zhi Bin

AU - Fu, Jie

AU - Xu, Yan

AU - Zhu, Dun Ru

PY - 2012/9/17

Y1 - 2012/9/17

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KW - X-ray diffraction

KW - catalysis

KW - hydrothermal synthesis

KW - polyoxometalates

KW - vanadates

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DO - 10.1002/chem.201200261

M3 - 文章

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A new "fully reduced" polyoxovanadate constructed from nanosized triangle-shaped [V^III₃V^IV₁₈P ₆O₆₀(DACH)₃]}^9- cluster anions exhibiting ferrimagnetic interactions

Abstract

Keywords

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