A new lithium-rich layer-structured cathode material with improved electrochemical performance and voltage maintenance

Xiaoqing Tian, Shengzhou Liu, Xueqin Jiang, Fei Ye, Rui Cai

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Lithium-rich layered oxides (LRLOs) are highly attractive cathode materials for next-generation lithium-ion batteries because of their high reversible capacity, but poor cycle performance and voltage decay are two main problems that strongly limit their practical applications. These challenges also apply to the Ru-based LRLOs of Li2RuO3. The Li2RuO3 cathode material is highly attractive because of their high conductivity and favourable electrochemical reaction kinetics. To overcome the problems associated with Li2RuO3, in contrast to normal single atom doping, here, we propose a Na, Cr co-doping strategy with the design of Li2−xNaxRu0.95Cr0.05O3 (x = 0, 0.02, 0.06, and 0.1) series materials. Cr doping increases capacity, and Na doping suppresses voltage decay. As a result, the discharge capacity of the optimal Li1.98Na0.02Ru0.95Cr0.05O3 sample over 240 mAh/g after 50 charge-discharge cycles at 0.2 C is maintained, and the capacity retention reaches a value of 80.5% compared with 69.1% for the undoped Li2RuO3. The value of the voltage decay in the Li1.98Na0.02Ru0.95Cr0.05O3 sample is 125 mV after 100 cycles at a rate of 1 C, and the voltage decay is 188.4 mV for the undoped Li2RuO3. This finding will expand the scope for designing novel layered electrodes with excellent performance.

Original languageEnglish
Pages (from-to)7547-7556
Number of pages10
JournalInternational Journal of Energy Research
Volume43
Issue number13
DOIs
StatePublished - 25 Oct 2019

Keywords

  • LiRuO
  • cathode material
  • co-doping strategy
  • lithium-rich layered oxides

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