A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies

Jingui Duan, Qianqian Li, Zhiyong Lu

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.

Original languageEnglish
Pages (from-to)2087-2090
Number of pages4
JournalCrystEngComm
Volume17
Issue number10
DOIs
StatePublished - 14 Mar 2015

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