A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies

Jingui Duan; Qianqian Li; Zhiyong Lu

doi:10.1039/c5ce00015g

A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies

Jingui Duan, Qianqian Li, Zhiyong Lu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A new porous coordination framework, [Cu₃(BTN)₂(H₂O)₃]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m² g^-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH₄ (excess amount: 174 cm³ g^-1), C₂H₄ (220 cm³ g^-1), C₂H₆ (299 cm³ g^-1) and CO₂ (298 cm³ g^-1) uptake capacities as well as good adsorption selectivities for C₂H₄ (12-145), C₂H₆ (15.5-380) and CO₂ (7.1-31.6) over CH₄ at 298 K.

Original language	English
Pages (from-to)	2087-2090
Number of pages	4
Journal	CrystEngComm
Volume	17
Issue number	10
DOIs	https://doi.org/10.1039/c5ce00015g
State	Published - 14 Mar 2015

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title = "A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies",

abstract = "A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.",

author = "Jingui Duan and Qianqian Li and Zhiyong Lu",

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T1 - A new mesoporous coordination polymer

T2 - Synthesis, structure, and gas adsorption studies

AU - Duan, Jingui

AU - Li, Qianqian

AU - Lu, Zhiyong

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Y1 - 2015/3/14

N2 - A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.

AB - A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.

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A new mesoporous coordination polymer: Synthesis, structure, and gas adsorption studies

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