Abstract
A new porous coordination framework, [Cu3(BTN)2(H2O)3]·xGuest (NJTU-1), with a large aromatic organic surface and remarkable mesopores, was synthesized and structurally characterized. It exhibits the second highest BET surface area of 2800 m2 g-1 among the interpenetrated PCPs. Additionally, this PCP also demonstrates high CH4 (excess amount: 174 cm3 g-1), C2H4 (220 cm3 g-1), C2H6 (299 cm3 g-1) and CO2 (298 cm3 g-1) uptake capacities as well as good adsorption selectivities for C2H4 (12-145), C2H6 (15.5-380) and CO2 (7.1-31.6) over CH4 at 298 K.
Original language | English |
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Pages (from-to) | 2087-2090 |
Number of pages | 4 |
Journal | CrystEngComm |
Volume | 17 |
Issue number | 10 |
DOIs | |
State | Published - 14 Mar 2015 |