A new method for preparing α-alumina ultrafiltration membrane at low sintering temperature

Weida Shi, Chao Yang, Minghui Qiu, Xianfu Chen, Yiqun Fan

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

α-Al2O3 has attracted much attention owing to its excellent organic solvent resistance and acid-base corrosion resistance. However, the preparation of α-Al2O3 ultrafiltration membranes by sol-gel method is still a challenge, because the formation of α-phase requires high temperature calcination and is accompanied by rapid grain growth. To reduce the phase transition temperature and obtain smaller grains, we started from a polymeric sol with particle size of approximately 3.7 nm, which was converted into α-Al2O3 at a low temperature of 1000 °C. Moreover, graphene oxide (GO) as the sacrificial layer was used to prevent the sol from penetrating into the macroporous support, and to obtain a high permeability α-Al2O3 ultrafiltration membrane. Because GO can be pyrolyzed at temperature above 500 °C, an ultra-thin and high pure water permeability α-Al2O3 ultrafiltration membrane was obtained at a low temperature of 1000 °C. The prepared α-Al2O3 ultrafiltration membrane showed a pure water permeability of up to 390 L m−2 h−1 bar−1 and a pore size of approximately 20 nm.

Original languageEnglish
Article number119992
JournalJournal of Membrane Science
Volume642
DOIs
StatePublished - 15 Feb 2022

Keywords

  • Graphene oxide
  • Phase transition
  • Ultrafiltration membrane
  • α-Alumina

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