A simple single-thiophene derivative assists efficient as-cast ternary organic solar cells through Förster resonance energy transfer

Xuyu Gao, Xianwang Tao, Yuanyuan Xu, Xiaochen Song, Huabin Wang, Ruitao Yu, Jian Ye, Youtian Tao

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

Developing ternary organic solar cells has been acknowledged as an effective method to improve the power conversion efficiency compared to the traditional binary counterparts. Therefore, developing low-cost third components is a “two birds one stone” strategy to synchronously realize high-performance ternary devices and reduce the material costs. In this work, a single-thiophene derivative (5E,5′E)-5,5′-(thiophene-2,5-diylbis(methaneylylidene))bis(3-ethylthiazolidine-2,4-dione) (TTZD) is designed and synthesized in a one-step process from low-cost raw materials. By incorporating 3 wt% TTZD into the PTB7-Th:IEICO-4F blends, ternary devices afforded promoted power conversion efficiency of 10.63%, higher than the 9.53% of the binary control. As investigated, blending appropriate amounts of TTZD negligibly disturbed the binary blend morphologies, but transferred supplemental photon energy to the host blends through the Förster resonance energy transfer process, resulting in enlarged photocurrent.

Original languageEnglish
Pages (from-to)12177-12183
Number of pages7
JournalNew Journal of Chemistry
Volume46
Issue number25
DOIs
StatePublished - 18 May 2022

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