TY - JOUR
T1 - A six-connected 3d europium coordination polymer assembled by 5-bromoisophthalic Acid (H2BIPA) and 1,10-phenanthroline (phen)
T2 - Synthesis, characterization and luminescent property
AU - Liu, Guang Xiang
AU - Huang, Rong Yi
AU - Huang, Liang Fang
AU - Xu, Heng
AU - Ren, Xiao Ming
PY - 2010/3
Y1 - 2010/3
N2 - A novel three-dimensional coordination polymer, [Eu2(phen) 2(BIPA)3]•2H2O (1) (BIPA = 5-bromoisophthalate), has been synthsized by the reaction 5-bromoisophthalic acid with Eu(NO3)3•6H2O under the hydrothermal conditions and characterized by IR, elemental analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic space group Pī and affords a three-dimensional (3D) six-connected α-Po network. Complex 1 showed the characteristic emission spectra of the EuIII and appeared to have good fluorescence properties.
AB - A novel three-dimensional coordination polymer, [Eu2(phen) 2(BIPA)3]•2H2O (1) (BIPA = 5-bromoisophthalate), has been synthsized by the reaction 5-bromoisophthalic acid with Eu(NO3)3•6H2O under the hydrothermal conditions and characterized by IR, elemental analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic space group Pī and affords a three-dimensional (3D) six-connected α-Po network. Complex 1 showed the characteristic emission spectra of the EuIII and appeared to have good fluorescence properties.
KW - 5-Bromoisophthalic acid
KW - Crystal structure
KW - Europium(III) coordination polymer
KW - Photophysical property
UR - http://www.scopus.com/inward/record.url?scp=77950858077&partnerID=8YFLogxK
U2 - 10.1007/s10870-010-9720-z
DO - 10.1007/s10870-010-9720-z
M3 - 文章
AN - SCOPUS:77950858077
SN - 1074-1542
VL - 40
SP - 283
EP - 287
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 3
ER -