Access to polyfunctionalized carbazoles through π-extension of 2-methyl-3-oxoacetate indoles

Yingying Guo; Zhoulu Wang; Ying Zhu; Qiaochu Zhang; Donghui Wei; Xiang Liu; Zhenqian Fu

doi:10.1039/c9qo01093a

Access to polyfunctionalized carbazoles through π-extension of 2-methyl-3-oxoacetate indoles

Yingying Guo, Zhoulu Wang, Ying Zhu, Qiaochu Zhang, Donghui Wei, Xiang Liu, Zhenqian Fu

School of energy science and engineering

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Formal [4 + 2] annulation of 2-methyl-3-oxoacetate indoles with naphthalene-1,4-dione and dialkyl acetylene dicarboxylates has been successfully developed. A structurally diverse set of polyfunctionalized carbazoles was efficiently synthesized in acceptable to excellent yields. This reaction features H₂O as the only by-product, has a broad substrate scope and proceeds under mild conditions.

Original language	English
Pages (from-to)	3741-3745
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	6
Issue number	22
DOIs	https://doi.org/10.1039/c9qo01093a
State	Published - 21 Nov 2019

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abstract = "Formal [4 + 2] annulation of 2-methyl-3-oxoacetate indoles with naphthalene-1,4-dione and dialkyl acetylene dicarboxylates has been successfully developed. A structurally diverse set of polyfunctionalized carbazoles was efficiently synthesized in acceptable to excellent yields. This reaction features H2O as the only by-product, has a broad substrate scope and proceeds under mild conditions.",

author = "Yingying Guo and Zhoulu Wang and Ying Zhu and Qiaochu Zhang and Donghui Wei and Xiang Liu and Zhenqian Fu",

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T1 - Access to polyfunctionalized carbazoles through π-extension of 2-methyl-3-oxoacetate indoles

AU - Guo, Yingying

AU - Wang, Zhoulu

AU - Zhu, Ying

AU - Zhang, Qiaochu

AU - Wei, Donghui

AU - Liu, Xiang

AU - Fu, Zhenqian

PY - 2019/11/21

Y1 - 2019/11/21

N2 - Formal [4 + 2] annulation of 2-methyl-3-oxoacetate indoles with naphthalene-1,4-dione and dialkyl acetylene dicarboxylates has been successfully developed. A structurally diverse set of polyfunctionalized carbazoles was efficiently synthesized in acceptable to excellent yields. This reaction features H2O as the only by-product, has a broad substrate scope and proceeds under mild conditions.

AB - Formal [4 + 2] annulation of 2-methyl-3-oxoacetate indoles with naphthalene-1,4-dione and dialkyl acetylene dicarboxylates has been successfully developed. A structurally diverse set of polyfunctionalized carbazoles was efficiently synthesized in acceptable to excellent yields. This reaction features H2O as the only by-product, has a broad substrate scope and proceeds under mild conditions.

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U2 - 10.1039/c9qo01093a

DO - 10.1039/c9qo01093a

M3 - 文章

AN - SCOPUS:85074640581

SN - 2052-4110

VL - 6

SP - 3741

EP - 3745

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 22

ER -

Access to polyfunctionalized carbazoles through π-extension of 2-methyl-3-oxoacetate indoles

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