An unusual approach to the synthesis of enantiomerically cis linear homoallylic alcohols based on the steric interaction mechanism of camphor scaffold

Chi Lik Ken Lee; Cheng Hsia Angeline Lee; Kui Thong Tan; Teck Peng Loh

doi:10.1021/ol049633z

An unusual approach to the synthesis of enantiomerically cis linear homoallylic alcohols based on the steric interaction mechanism of camphor scaffold

Chi Lik Ken Lee, Cheng Hsia Angeline Lee, Kui Thong Tan, Teck Peng Loh

National University of Singapore

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

Camphor is used as the chiral auxiliary for the enantioselective synthesis of cis linear homoallylic alcohols. A range of catalysts, aldehydes, and solvents were investigated to obtain the optimum yield, enantioselectivity, and cis olefinic geometry.

Original language	English
Pages (from-to)	1281-1283
Number of pages	3
Journal	Organic Letters
Volume	6
Issue number	8
DOIs	https://doi.org/10.1021/ol049633z
State	Published - 15 Apr 2004
Externally published	Yes

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10.1021/ol049633z

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title = "An unusual approach to the synthesis of enantiomerically cis linear homoallylic alcohols based on the steric interaction mechanism of camphor scaffold",

abstract = "Camphor is used as the chiral auxiliary for the enantioselective synthesis of cis linear homoallylic alcohols. A range of catalysts, aldehydes, and solvents were investigated to obtain the optimum yield, enantioselectivity, and cis olefinic geometry.",

author = "Lee, {Chi Lik Ken} and Lee, {Cheng Hsia Angeline} and Tan, {Kui Thong} and Loh, {Teck Peng}",

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AU - Lee, Chi Lik Ken

AU - Lee, Cheng Hsia Angeline

AU - Tan, Kui Thong

AU - Loh, Teck Peng

PY - 2004/4/15

Y1 - 2004/4/15

N2 - Camphor is used as the chiral auxiliary for the enantioselective synthesis of cis linear homoallylic alcohols. A range of catalysts, aldehydes, and solvents were investigated to obtain the optimum yield, enantioselectivity, and cis olefinic geometry.

AB - Camphor is used as the chiral auxiliary for the enantioselective synthesis of cis linear homoallylic alcohols. A range of catalysts, aldehydes, and solvents were investigated to obtain the optimum yield, enantioselectivity, and cis olefinic geometry.

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DO - 10.1021/ol049633z

M3 - 文章

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JO - Organic Letters

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An unusual approach to the synthesis of enantiomerically cis linear homoallylic alcohols based on the steric interaction mechanism of camphor scaffold

Abstract

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