Catalyst-free: N -formylation of amines using BH3NH3 and CO2 under mild conditions

Tian Xiang Zhao; Gao Wen Zhai; Jian Liang; Ping Li; Xing Bang Hu; You Ting Wu

doi:10.1039/c7cc03860g

Catalyst-free: N -formylation of amines using BH₃NH₃ and CO₂ under mild conditions

Tian Xiang Zhao, Gao Wen Zhai, Jian Liang, Ping Li, Xing Bang Hu, You Ting Wu

Nanjing University

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

The catalyst-free N-formylation of amines using CO₂ as the C₁ source and BH₃NH₃ as the reductant has been developed for the first time. The corresponding formylated products of both primary and secondary amines are obtained in good to excellent yields (up to 96% of isolated yield) under mild conditions.

Original language	English
Pages (from-to)	8046-8049
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	57
DOIs	https://doi.org/10.1039/c7cc03860g
State	Published - 2017
Externally published	Yes

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title = "Catalyst-free: N -formylation of amines using BH3NH3 and CO2 under mild conditions",

abstract = "The catalyst-free N-formylation of amines using CO2 as the C1 source and BH3NH3 as the reductant has been developed for the first time. The corresponding formylated products of both primary and secondary amines are obtained in good to excellent yields (up to 96% of isolated yield) under mild conditions.",

author = "Zhao, {Tian Xiang} and Zhai, {Gao Wen} and Jian Liang and Ping Li and Hu, {Xing Bang} and Wu, {You Ting}",

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T2 - N -formylation of amines using BH3NH3 and CO2 under mild conditions

AU - Zhao, Tian Xiang

AU - Zhai, Gao Wen

AU - Liang, Jian

AU - Li, Ping

AU - Hu, Xing Bang

AU - Wu, You Ting

PY - 2017

Y1 - 2017

N2 - The catalyst-free N-formylation of amines using CO2 as the C1 source and BH3NH3 as the reductant has been developed for the first time. The corresponding formylated products of both primary and secondary amines are obtained in good to excellent yields (up to 96% of isolated yield) under mild conditions.

AB - The catalyst-free N-formylation of amines using CO2 as the C1 source and BH3NH3 as the reductant has been developed for the first time. The corresponding formylated products of both primary and secondary amines are obtained in good to excellent yields (up to 96% of isolated yield) under mild conditions.

UR - http://www.scopus.com/inward/record.url?scp=85024118547&partnerID=8YFLogxK

U2 - 10.1039/c7cc03860g

DO - 10.1039/c7cc03860g

M3 - 文章

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AN - SCOPUS:85024118547

SN - 1359-7345

VL - 53

SP - 8046

EP - 8049

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Catalyst-free: N -formylation of amines using BH₃NH₃ and CO₂ under mild conditions

Abstract

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