Catalytic hypervalent iodine oxidation of alcohols to corresponding aldehydes or ketones using 2,2,6,6-tetramethylpiperidinyl-1-oxy and potassium peroxodisulfate

Chenjie Zhu; Lei Ji; Yunyang Wei

doi:10.1007/s00706-010-0260-1

Catalytic hypervalent iodine oxidation of alcohols to corresponding aldehydes or ketones using 2,2,6,6-tetramethylpiperidinyl-1-oxy and potassium peroxodisulfate

Chenjie Zhu, Lei Ji, Yunyang Wei

Nanjing University of Science and Technology

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

An efficient, facile, and mild oxidation of alcohols to the corresponding aldehydes or ketones with potassium peroxodisulfate and 2,2,6,6- tetramethylpiperidinyl-1-oxy in the presence of a catalytic amount of iodobenzene is reported. The oxidation proceeded in a mixed solvent to afford carbonyl compounds in moderate to excellent yields. A possible mechanism for the oxidation is proposed.

Original language	English
Pages (from-to)	327-331
Number of pages	5
Journal	Monatshefte fur Chemie
Volume	141
Issue number	3
DOIs	https://doi.org/10.1007/s00706-010-0260-1
State	Published - Mar 2010
Externally published	Yes

Keywords

Alcohols
Catalysis
Hypervalent iodine
Oxidations
TEMPO

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10.1007/s00706-010-0260-1

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abstract = "An efficient, facile, and mild oxidation of alcohols to the corresponding aldehydes or ketones with potassium peroxodisulfate and 2,2,6,6- tetramethylpiperidinyl-1-oxy in the presence of a catalytic amount of iodobenzene is reported. The oxidation proceeded in a mixed solvent to afford carbonyl compounds in moderate to excellent yields. A possible mechanism for the oxidation is proposed.",

keywords = "Alcohols, Catalysis, Hypervalent iodine, Oxidations, TEMPO",

author = "Chenjie Zhu and Lei Ji and Yunyang Wei",

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AU - Zhu, Chenjie

AU - Ji, Lei

AU - Wei, Yunyang

PY - 2010/3

Y1 - 2010/3

N2 - An efficient, facile, and mild oxidation of alcohols to the corresponding aldehydes or ketones with potassium peroxodisulfate and 2,2,6,6- tetramethylpiperidinyl-1-oxy in the presence of a catalytic amount of iodobenzene is reported. The oxidation proceeded in a mixed solvent to afford carbonyl compounds in moderate to excellent yields. A possible mechanism for the oxidation is proposed.

AB - An efficient, facile, and mild oxidation of alcohols to the corresponding aldehydes or ketones with potassium peroxodisulfate and 2,2,6,6- tetramethylpiperidinyl-1-oxy in the presence of a catalytic amount of iodobenzene is reported. The oxidation proceeded in a mixed solvent to afford carbonyl compounds in moderate to excellent yields. A possible mechanism for the oxidation is proposed.

KW - Alcohols

KW - Catalysis

KW - Hypervalent iodine

KW - Oxidations

KW - TEMPO

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U2 - 10.1007/s00706-010-0260-1

DO - 10.1007/s00706-010-0260-1

M3 - 文章

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JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 3

ER -

Catalytic hypervalent iodine oxidation of alcohols to corresponding aldehydes or ketones using 2,2,6,6-tetramethylpiperidinyl-1-oxy and potassium peroxodisulfate

Abstract

Keywords

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