Catalytic hypervalent iodine oxidation of alcohols to the corresponding carbonyl compounds using N-hydroxyphthalimide (NHPI) and m-chloroperbenzoic acid

Chenjie Zhu; Lei Ji; Qian Zhang; Yunyang Wei

doi:10.1139/V10-007

Catalytic hypervalent iodine oxidation of alcohols to the corresponding carbonyl compounds using N-hydroxyphthalimide (NHPI) and m-chloroperbenzoic acid

Chenjie Zhu, Lei Ji, Qian Zhang, Yunyang Wei

Nanjing University of Science and Technology

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

An efficient, facile, and mild oxidation of alcohols to the corresponding carbonyl compounds with m-chloroperbenzoic acid (mCPBA) and N-hydroxyphthalimide (NHPI) in the presence of a catalytic amount of iodobenzene was reported. The oxidation proceeded in mixed solvent at room temperature to afford carbonyl compounds in excellent yields. A possible mechanism for the oxidation was proposed.

Original language	English
Pages (from-to)	362-366
Number of pages	5
Journal	Canadian Journal of Chemistry
Volume	88
Issue number	4
DOIs	https://doi.org/10.1139/V10-007
State	Published - Apr 2010
Externally published	Yes

Keywords

Alcohols
Iodobenzene
M-chloroperbenzoic acid (mCPBA)
N-hydroxyphthalimide (NHPI)
Oxidation

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10.1139/V10-007

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abstract = "An efficient, facile, and mild oxidation of alcohols to the corresponding carbonyl compounds with m-chloroperbenzoic acid (mCPBA) and N-hydroxyphthalimide (NHPI) in the presence of a catalytic amount of iodobenzene was reported. The oxidation proceeded in mixed solvent at room temperature to afford carbonyl compounds in excellent yields. A possible mechanism for the oxidation was proposed.",

keywords = "Alcohols, Iodobenzene, M-chloroperbenzoic acid (mCPBA), N-hydroxyphthalimide (NHPI), Oxidation",

author = "Chenjie Zhu and Lei Ji and Qian Zhang and Yunyang Wei",

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volume = "88",

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T1 - Catalytic hypervalent iodine oxidation of alcohols to the corresponding carbonyl compounds using N-hydroxyphthalimide (NHPI) and m-chloroperbenzoic acid

AU - Zhu, Chenjie

AU - Ji, Lei

AU - Zhang, Qian

AU - Wei, Yunyang

PY - 2010/4

Y1 - 2010/4

N2 - An efficient, facile, and mild oxidation of alcohols to the corresponding carbonyl compounds with m-chloroperbenzoic acid (mCPBA) and N-hydroxyphthalimide (NHPI) in the presence of a catalytic amount of iodobenzene was reported. The oxidation proceeded in mixed solvent at room temperature to afford carbonyl compounds in excellent yields. A possible mechanism for the oxidation was proposed.

AB - An efficient, facile, and mild oxidation of alcohols to the corresponding carbonyl compounds with m-chloroperbenzoic acid (mCPBA) and N-hydroxyphthalimide (NHPI) in the presence of a catalytic amount of iodobenzene was reported. The oxidation proceeded in mixed solvent at room temperature to afford carbonyl compounds in excellent yields. A possible mechanism for the oxidation was proposed.

KW - Alcohols

KW - Iodobenzene

KW - M-chloroperbenzoic acid (mCPBA)

KW - N-hydroxyphthalimide (NHPI)

KW - Oxidation

UR - http://www.scopus.com/inward/record.url?scp=77950259340&partnerID=8YFLogxK

U2 - 10.1139/V10-007

DO - 10.1139/V10-007

M3 - 文章

AN - SCOPUS:77950259340

SN - 0008-4042

VL - 88

SP - 362

EP - 366

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 4

ER -

Catalytic hypervalent iodine oxidation of alcohols to the corresponding carbonyl compounds using N-hydroxyphthalimide (NHPI) and m-chloroperbenzoic acid

Abstract

Keywords

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