Chemoselective Transfer Hydrogenation of Aldehydes and Ketones with a Heterogeneous Iridium Catalyst in Water

Zhi Wang; Lei Huang; Longfei Geng; Rizhi Chen; Weihong Xing; Yong Wang; Jun Huang

doi:10.1007/s10562-014-1473-4

Chemoselective Transfer Hydrogenation of Aldehydes and Ketones with a Heterogeneous Iridium Catalyst in Water

Zhi Wang, Lei Huang, Longfei Geng, Rizhi Chen, Weihong Xing, Yong Wang, Jun Huang

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Ir nanocatalyst Ir@CN was prepared by pyrolysis of the IrCl₃ complex with 1,10-phenanthroline in the activated carbon. The iridium nanocatalyst Ir@CN was highly selective for the transfer hydrogenation of aldehydes and ketones including benzaldehyde derivatives, and the hydrogenative alkylation of C=O bonds was suppressed effectively. The iridium nanocatalyst Ir@CN is a heterogeneous catalyst and can be reused several times for the transfer hydrogenation of aldehydes and ketones.

Original language	English
Article number	1473
Pages (from-to)	1008-1013
Number of pages	6
Journal	Catalysis Letters
Volume	145
Issue number	4
DOIs	https://doi.org/10.1007/s10562-014-1473-4
State	Published - 1 Apr 2015

Keywords

Aldehydes
Heterogeneous catalysts
Ir nanocatalyst
Ketones
Transfer hydrogenation

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10.1007/s10562-014-1473-4

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title = "Chemoselective Transfer Hydrogenation of Aldehydes and Ketones with a Heterogeneous Iridium Catalyst in Water",

abstract = "Ir nanocatalyst Ir@CN was prepared by pyrolysis of the IrCl3 complex with 1,10-phenanthroline in the activated carbon. The iridium nanocatalyst Ir@CN was highly selective for the transfer hydrogenation of aldehydes and ketones including benzaldehyde derivatives, and the hydrogenative alkylation of C=O bonds was suppressed effectively. The iridium nanocatalyst Ir@CN is a heterogeneous catalyst and can be reused several times for the transfer hydrogenation of aldehydes and ketones.",

keywords = "Aldehydes, Heterogeneous catalysts, Ir nanocatalyst, Ketones, Transfer hydrogenation",

author = "Zhi Wang and Lei Huang and Longfei Geng and Rizhi Chen and Weihong Xing and Yong Wang and Jun Huang",

note = "Publisher Copyright: {\textcopyright} 2015 Springer Science+Business Media New York.",

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doi = "10.1007/s10562-014-1473-4",

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TY - JOUR

T1 - Chemoselective Transfer Hydrogenation of Aldehydes and Ketones with a Heterogeneous Iridium Catalyst in Water

AU - Wang, Zhi

AU - Huang, Lei

AU - Geng, Longfei

AU - Chen, Rizhi

AU - Xing, Weihong

AU - Wang, Yong

AU - Huang, Jun

PY - 2015/4/1

Y1 - 2015/4/1

N2 - Ir nanocatalyst Ir@CN was prepared by pyrolysis of the IrCl3 complex with 1,10-phenanthroline in the activated carbon. The iridium nanocatalyst Ir@CN was highly selective for the transfer hydrogenation of aldehydes and ketones including benzaldehyde derivatives, and the hydrogenative alkylation of C=O bonds was suppressed effectively. The iridium nanocatalyst Ir@CN is a heterogeneous catalyst and can be reused several times for the transfer hydrogenation of aldehydes and ketones.

AB - Ir nanocatalyst Ir@CN was prepared by pyrolysis of the IrCl3 complex with 1,10-phenanthroline in the activated carbon. The iridium nanocatalyst Ir@CN was highly selective for the transfer hydrogenation of aldehydes and ketones including benzaldehyde derivatives, and the hydrogenative alkylation of C=O bonds was suppressed effectively. The iridium nanocatalyst Ir@CN is a heterogeneous catalyst and can be reused several times for the transfer hydrogenation of aldehydes and ketones.

KW - Aldehydes

KW - Heterogeneous catalysts

KW - Ir nanocatalyst

KW - Ketones

KW - Transfer hydrogenation

UR - http://www.scopus.com/inward/record.url?scp=84936860464&partnerID=8YFLogxK

U2 - 10.1007/s10562-014-1473-4

DO - 10.1007/s10562-014-1473-4

M3 - 文章

AN - SCOPUS:84936860464

SN - 1011-372X

VL - 145

SP - 1008

EP - 1013

JO - Catalysis Letters

JF - Catalysis Letters

IS - 4

M1 - 1473

ER -

Chemoselective Transfer Hydrogenation of Aldehydes and Ketones with a Heterogeneous Iridium Catalyst in Water

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Keywords

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