Chiral molecule-based ferrimagnets with helical structures

He Rui Wen, Cai Feng Wang, Yi Zhi Li, Jing Lin Zuo, You Song, Xiao Zeng You

Research output: Contribution to journalArticlepeer-review

96 Scopus citations

Abstract

Two enantiopure one-dimensional complexes with helical structures, [Mn 3((R,R)-Salcy)3(H2O)2Fe(CN) 6·2H2O]n (1) and [Mn3((S,S)- Salcy)3-(H2O)2Fe(CN)6·2H 2O]n (2) [Salcy = N,N′-(1,2-cyclohexanediylethylene) bis(salicylideneiminato) dianion], have been synthesized and characterized. Magnetic studies show that both complexes are ferrimagnets with the magnetic transition temperature at 3 K.

Original languageEnglish
Pages (from-to)7032-7034
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number18
DOIs
StatePublished - 4 Sep 2006
Externally publishedYes

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