Continuous-flow electro-oxidative coupling of sulfides with activated methylene compounds leading to sulfur ylides

Chengkou Liu; Yang Lin; Chen Cai; Chengcheng Yuan; Zheng Fang; Kai Guo

doi:10.1039/d1gc00226k

Continuous-flow electro-oxidative coupling of sulfides with activated methylene compounds leading to sulfur ylides

Chengkou Liu, Yang Lin, Chen Cai, Chengcheng Yuan, Zheng Fang, Kai Guo

COLLEGE OF BIOTECHNOLOGY AND PHARMACEUTICAL ENGINEERING

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

An unprecedentedly straightforward electro-oxidative coupling of sulfides with activated methylene compounds to synthesize sulfur ylides has been developed. Good to excellent yields can be obtained under catalyst- and oxidant-free conditions at room temperature. Owing to the use of continuous-flow electrochemical setups, this green, mild and practical electrosynthesis features high efficiency and excellent functional group tolerance and is easy to scale up.

Original language	English
Pages (from-to)	2956-2961
Number of pages	6
Journal	Green Chemistry
Volume	23
Issue number	8
DOIs	https://doi.org/10.1039/d1gc00226k
State	Published - 21 Apr 2021

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title = "Continuous-flow electro-oxidative coupling of sulfides with activated methylene compounds leading to sulfur ylides",

abstract = "An unprecedentedly straightforward electro-oxidative coupling of sulfides with activated methylene compounds to synthesize sulfur ylides has been developed. Good to excellent yields can be obtained under catalyst- and oxidant-free conditions at room temperature. Owing to the use of continuous-flow electrochemical setups, this green, mild and practical electrosynthesis features high efficiency and excellent functional group tolerance and is easy to scale up.",

author = "Chengkou Liu and Yang Lin and Chen Cai and Chengcheng Yuan and Zheng Fang and Kai Guo",

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AU - Liu, Chengkou

AU - Lin, Yang

AU - Cai, Chen

AU - Yuan, Chengcheng

AU - Fang, Zheng

AU - Guo, Kai

PY - 2021/4/21

Y1 - 2021/4/21

N2 - An unprecedentedly straightforward electro-oxidative coupling of sulfides with activated methylene compounds to synthesize sulfur ylides has been developed. Good to excellent yields can be obtained under catalyst- and oxidant-free conditions at room temperature. Owing to the use of continuous-flow electrochemical setups, this green, mild and practical electrosynthesis features high efficiency and excellent functional group tolerance and is easy to scale up.

AB - An unprecedentedly straightforward electro-oxidative coupling of sulfides with activated methylene compounds to synthesize sulfur ylides has been developed. Good to excellent yields can be obtained under catalyst- and oxidant-free conditions at room temperature. Owing to the use of continuous-flow electrochemical setups, this green, mild and practical electrosynthesis features high efficiency and excellent functional group tolerance and is easy to scale up.

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M3 - 文章

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SP - 2956

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Continuous-flow electro-oxidative coupling of sulfides with activated methylene compounds leading to sulfur ylides

Abstract

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