Copper diphosphonates with zero-, one- and two-dimensional structures: Ferrimagnetism in layer compound Cu3(ImhedpH)2·2H2O [ImhedpH4 = (1-C3H3N2)CH2C(OH)(PO3H2)2]

Deng Ke Cao; Xiao Ji Xie; Yi Zhi Li; Li Min Zheng

doi:10.1039/b805487h

Copper diphosphonates with zero-, one- and two-dimensional structures: Ferrimagnetism in layer compound Cu₃(ImhedpH)₂·2H₂O [ImhedpH₄ = (1-C₃H₃N₂)CH₂C(OH)(PO₃H₂)₂]

Deng Ke Cao, Xiao Ji Xie, Yi Zhi Li, Li Min Zheng

Nanjing University

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40 Scopus citations

Abstract

Reactions of CuSO₄ with 2-(1-imidazole)-1-hydroxy-1,1′-ethylidenediphosphonic acid (ImhedpH₄) under hydrothermal conditions at different temperatures lead to four new metal phosphonates: Cu(ImhedpH₃)₂(H₂O)·2H₂O (1), Cu(ImhedpH₃)₂ (2), Cu₃(ImhedpH₂)₂(ImhedpH₃)₂·4H₂O (3), and Cu₃(ImhedpH)₂·2H₂O (4). Compounds 1 and 2 have mononuclear structures in which the Cu atoms adopt square pyramidal and square planar geometries, respectively. In compound 3, a chain structure is observed where the Cu₃(ImhedpH₂)₂(ImhedpH₃)₂ trimer units are connected by edge-sharing of the (Cu(2)O₅) square pyramids. Compound 4 exhibits a layer structure made up of Cu₃(ImhedpH)₂ trimer units. The connection of trimers through corner-sharing of (Cu(1)O₄) and (CPO₃) tetrahedra results in a two-dimensional layer containing 8- and 16-membered rings. The imidazole groups are grafted on the two sides of the layer. Magnetic studies reveal that ferromagnetic interactions are mediated in 3, while for compound 4, ferrimagnetism is observed below 5.8 K.

Original language	English
Pages (from-to)	5008-5015
Number of pages	8
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	37
DOIs	https://doi.org/10.1039/b805487h
State	Published - 7 Aug 2008
Externally published	Yes

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@article{7a26cdd544d6410db59e1b9f798827aa,

title = "Copper diphosphonates with zero-, one- and two-dimensional structures: Ferrimagnetism in layer compound Cu3(ImhedpH)2·2H2O [ImhedpH4 = (1-C3H3N2)CH2C(OH)(PO3H2)2]",

abstract = "Reactions of CuSO4 with 2-(1-imidazole)-1-hydroxy-1,1′-ethylidenediphosphonic acid (ImhedpH4) under hydrothermal conditions at different temperatures lead to four new metal phosphonates: Cu(ImhedpH3)2(H2O)·2H2O (1), Cu(ImhedpH3)2 (2), Cu3(ImhedpH2)2(ImhedpH3)2·4H2O (3), and Cu3(ImhedpH)2·2H2O (4). Compounds 1 and 2 have mononuclear structures in which the Cu atoms adopt square pyramidal and square planar geometries, respectively. In compound 3, a chain structure is observed where the Cu3(ImhedpH2)2(ImhedpH3)2 trimer units are connected by edge-sharing of the (Cu(2)O5) square pyramids. Compound 4 exhibits a layer structure made up of Cu3(ImhedpH)2 trimer units. The connection of trimers through corner-sharing of (Cu(1)O4) and (CPO3) tetrahedra results in a two-dimensional layer containing 8- and 16-membered rings. The imidazole groups are grafted on the two sides of the layer. Magnetic studies reveal that ferromagnetic interactions are mediated in 3, while for compound 4, ferrimagnetism is observed below 5.8 K.",

author = "Cao, {Deng Ke} and Xie, {Xiao Ji} and Li, {Yi Zhi} and Zheng, {Li Min}",

year = "2008",

month = aug,

day = "7",

doi = "10.1039/b805487h",

language = "英语",

pages = "5008--5015",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "37",

}

Copper diphosphonates with zero-, one- and two-dimensional structures: Ferrimagnetism in layer compound Cu₃(ImhedpH)₂·2H₂O [ImhedpH₄ = (1-C₃H₃N₂)CH₂C(OH)(PO₃H₂)₂]. / Cao, Deng Ke; Xie, Xiao Ji; Li, Yi Zhi et al.
In: Journal of the Chemical Society. Dalton Transactions, No. 37, 07.08.2008, p. 5008-5015.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Copper diphosphonates with zero-, one- and two-dimensional structures

T2 - Ferrimagnetism in layer compound Cu3(ImhedpH)2·2H2O [ImhedpH4 = (1-C3H3N2)CH2C(OH)(PO3H2)2]

AU - Cao, Deng Ke

AU - Xie, Xiao Ji

AU - Li, Yi Zhi

AU - Zheng, Li Min

PY - 2008/8/7

Y1 - 2008/8/7

N2 - Reactions of CuSO4 with 2-(1-imidazole)-1-hydroxy-1,1′-ethylidenediphosphonic acid (ImhedpH4) under hydrothermal conditions at different temperatures lead to four new metal phosphonates: Cu(ImhedpH3)2(H2O)·2H2O (1), Cu(ImhedpH3)2 (2), Cu3(ImhedpH2)2(ImhedpH3)2·4H2O (3), and Cu3(ImhedpH)2·2H2O (4). Compounds 1 and 2 have mononuclear structures in which the Cu atoms adopt square pyramidal and square planar geometries, respectively. In compound 3, a chain structure is observed where the Cu3(ImhedpH2)2(ImhedpH3)2 trimer units are connected by edge-sharing of the (Cu(2)O5) square pyramids. Compound 4 exhibits a layer structure made up of Cu3(ImhedpH)2 trimer units. The connection of trimers through corner-sharing of (Cu(1)O4) and (CPO3) tetrahedra results in a two-dimensional layer containing 8- and 16-membered rings. The imidazole groups are grafted on the two sides of the layer. Magnetic studies reveal that ferromagnetic interactions are mediated in 3, while for compound 4, ferrimagnetism is observed below 5.8 K.

AB - Reactions of CuSO4 with 2-(1-imidazole)-1-hydroxy-1,1′-ethylidenediphosphonic acid (ImhedpH4) under hydrothermal conditions at different temperatures lead to four new metal phosphonates: Cu(ImhedpH3)2(H2O)·2H2O (1), Cu(ImhedpH3)2 (2), Cu3(ImhedpH2)2(ImhedpH3)2·4H2O (3), and Cu3(ImhedpH)2·2H2O (4). Compounds 1 and 2 have mononuclear structures in which the Cu atoms adopt square pyramidal and square planar geometries, respectively. In compound 3, a chain structure is observed where the Cu3(ImhedpH2)2(ImhedpH3)2 trimer units are connected by edge-sharing of the (Cu(2)O5) square pyramids. Compound 4 exhibits a layer structure made up of Cu3(ImhedpH)2 trimer units. The connection of trimers through corner-sharing of (Cu(1)O4) and (CPO3) tetrahedra results in a two-dimensional layer containing 8- and 16-membered rings. The imidazole groups are grafted on the two sides of the layer. Magnetic studies reveal that ferromagnetic interactions are mediated in 3, while for compound 4, ferrimagnetism is observed below 5.8 K.

UR - http://www.scopus.com/inward/record.url?scp=52349120239&partnerID=8YFLogxK

U2 - 10.1039/b805487h

DO - 10.1039/b805487h

M3 - 文章

C2 - 18802613

AN - SCOPUS:52349120239

SN - 1470-479X

SP - 5008

EP - 5015

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 37

ER -

Copper diphosphonates with zero-, one- and two-dimensional structures: Ferrimagnetism in layer compound Cu₃(ImhedpH)₂·2H₂O [ImhedpH₄ = (1-C₃H₃N₂)CH₂C(OH)(PO₃H₂)₂]

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