Crystal structure of dimethyl 3,3′-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate

Hong Shun Sun, Yu Long Li, Hong Jiang, Ning Xu, Hong Xu

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

In the title compound, C27H21N3O6·C2H5OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)°; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)°. In the crystal, molecules are linked by N - H⋯O and O - H⋯O hydrogen bonds and weak C - H⋯π interactions into a three-dimensional supramolecular architecture. A void of 33.0 (7) Å3 is observed in the crystal structure. The solvent ethanol molecule acts as a donor, forming an O - H⋯O hydrogen bond, reinforcing the framework structure.

Original languageEnglish
Pages (from-to)370-372
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number11
DOIs
StatePublished - 4 Oct 2014

Keywords

  • MRI contrast agent
  • crystal structure
  • indole

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