Dehydrative allylation of P-H species under metal-free conditions

Xiaobo Yang; Bowen Li; Huicong Xing; Ju Qiu; Teck Peng Loh; Peizhong Xie

doi:10.1039/d1gc00191d

Dehydrative allylation of P-H species under metal-free conditions

Xiaobo Yang, Bowen Li, Huicong Xing, Ju Qiu, Teck Peng Loh, Peizhong Xie

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

An environmentally benign protocol for C-P bond construction was developed under metal- and solvent-free conditions. In the presence of B(C₆F₅)₃, wide-spectrum P-H species, including dialkylphosphite, hypophosphite ester, and secondary phosphine oxides, can be successfully incorporated into the dehydrative cross-coupling process with allylic alcohols delivering the corresponding allylic organophosphorus compounds in high yields.

Original language	English
Pages (from-to)	1633-1637
Number of pages	5
Journal	Green Chemistry
Volume	23
Issue number	4
DOIs	https://doi.org/10.1039/d1gc00191d
State	Published - 21 Feb 2021

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abstract = "An environmentally benign protocol for C-P bond construction was developed under metal- and solvent-free conditions. In the presence of B(C6F5)3, wide-spectrum P-H species, including dialkylphosphite, hypophosphite ester, and secondary phosphine oxides, can be successfully incorporated into the dehydrative cross-coupling process with allylic alcohols delivering the corresponding allylic organophosphorus compounds in high yields.",

author = "Xiaobo Yang and Bowen Li and Huicong Xing and Ju Qiu and Loh, {Teck Peng} and Peizhong Xie",

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AU - Li, Bowen

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AU - Qiu, Ju

AU - Loh, Teck Peng

AU - Xie, Peizhong

PY - 2021/2/21

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N2 - An environmentally benign protocol for C-P bond construction was developed under metal- and solvent-free conditions. In the presence of B(C6F5)3, wide-spectrum P-H species, including dialkylphosphite, hypophosphite ester, and secondary phosphine oxides, can be successfully incorporated into the dehydrative cross-coupling process with allylic alcohols delivering the corresponding allylic organophosphorus compounds in high yields.

AB - An environmentally benign protocol for C-P bond construction was developed under metal- and solvent-free conditions. In the presence of B(C6F5)3, wide-spectrum P-H species, including dialkylphosphite, hypophosphite ester, and secondary phosphine oxides, can be successfully incorporated into the dehydrative cross-coupling process with allylic alcohols delivering the corresponding allylic organophosphorus compounds in high yields.

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Dehydrative allylation of P-H species under metal-free conditions

Abstract

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