TY - JOUR
T1 - Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation
AU - Zhang, Suoying
AU - Li, Hang
AU - Liu, Pengfei
AU - Ma, Lu
AU - Li, Licheng
AU - Zhang, Weina
AU - Meng, Fanchen
AU - Li, Long
AU - Yang, Zhuhong
AU - Wu, Tianpin
AU - Huo, Fengwei
AU - Lu, Jun
N1 - Publisher Copyright:
© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2019/12/1
Y1 - 2019/12/1
N2 - The controllable self-assembly of nanomaterials remains a great challenge in nanotechnological applications, especially for the hierarchical structure with high complexity. Herein, by taking the advantage of highly dispersed metal nodes and mild thermal stability of metal-organic frameworks (MOFs), the self-assembly of nanoparticles is directed from MOFs to construct CuO hierarchical structures, which have an inherited octahedral framework consisting of the microspheres, nanowires, and polyhedrons, respectively. Unlike the conventional self-assembly in a solution media (such as solvent and molten solid), the assembly in this work is the first demonstration through a solution-free approach. Moreover, compared to the general MOF-derived CuO octahedron, the assembled hierarchical CuO structure exhibits much enhanced catalytic activity in CO oxidation thanks to the exposure of more active sites during the assembly.
AB - The controllable self-assembly of nanomaterials remains a great challenge in nanotechnological applications, especially for the hierarchical structure with high complexity. Herein, by taking the advantage of highly dispersed metal nodes and mild thermal stability of metal-organic frameworks (MOFs), the self-assembly of nanoparticles is directed from MOFs to construct CuO hierarchical structures, which have an inherited octahedral framework consisting of the microspheres, nanowires, and polyhedrons, respectively. Unlike the conventional self-assembly in a solution media (such as solvent and molten solid), the assembly in this work is the first demonstration through a solution-free approach. Moreover, compared to the general MOF-derived CuO octahedron, the assembled hierarchical CuO structure exhibits much enhanced catalytic activity in CO oxidation thanks to the exposure of more active sites during the assembly.
KW - catalyst
KW - hierarchical structure
KW - metal-organic framework
KW - self-assembly
KW - solution-free
UR - http://www.scopus.com/inward/record.url?scp=85075084124&partnerID=8YFLogxK
U2 - 10.1002/aenm.201901754
DO - 10.1002/aenm.201901754
M3 - 文章
AN - SCOPUS:85075084124
SN - 1614-6832
VL - 9
JO - Advanced Energy Materials
JF - Advanced Energy Materials
IS - 48
M1 - 1901754
ER -
