Effects of Doping CeO2, Er2O3 on Properties of TiO2-SiO2 Ceramics for Catalyst Supporter of deNOx

Zhu Shemin, Shen Yuesong, Li Weifeng, Liu Yayun

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9 Scopus citations

Abstract

Effects of doping CeO2 and Er2O3 on the mechanical strength, thermal expansion coefficient, sintering temperature of TiO2-SiO2 ceramics were investigated. The experimental results and the microscopic analysis of SEM, XRD, TG-DSC, FT-IR and TEM show that adding CeO2 and Er2O3 into TiO2-SiO2 ceramics can prohibit the growth of its crystal grains, make their size uniform and form them into a dense structure, which finally enhance its mechanical behaviors, and the lower thermal expansion coefficient that leads to an excellent property of thermal shock resistance. After the reforming TiO2-SiO2 ceramics doped by CeO2 was sintered at 1380 °C, the bending strength reached to 83 MPa, and the thermal expansion coefficient was 9.8 × 10-6/°C within the temperature range of 25 ∼ 800 °C, which provides a promising basis of making equipped honeycomb catalyst of deNox.

Original languageEnglish
Pages (from-to)234-238
Number of pages5
JournalJournal of Rare Earths
Volume24
Issue number1 SUPPL. 1
DOIs
StatePublished - Dec 2006

Keywords

  • bending strenght
  • ceramics of TiO-SiO
  • cerium oxide
  • deNO
  • erbium oxide
  • rare earths
  • thermal expansion

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