Effects of organoamine template and transition metal coordination mode on the self-assembly of reduced polyoxomolybdenum phosphate

Dawei Yan; Jie Fu; Lei Zheng; Zhibin Zhang; Yan Xu; Xiaolei Zhu; Dunru Zhu

doi:10.1039/c1ce05417a

Effects of organoamine template and transition metal coordination mode on the self-assembly of reduced polyoxomolybdenum phosphate

Dawei Yan, Jie Fu, Lei Zheng, Zhibin Zhang, Yan Xu, Xiaolei Zhu, Dunru Zhu

College of Chemical Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Four new compounds of reduced polyoxomolybdenum phosphate (v) with the formula (H₂enMe)₄(MnH₂O)₂{Mn[Mo ₆O₁₂(OH)₃(HPO₄)₂(PO ₄)₂]₂}·5H₂O (1) (enMe = 1,2-diaminopropane), (H₃N(CH₂)₄NH ₃)₄(MnH₂O)₂{Mn[Mo₆O ₁₂(OH)₃(HPO₄)₂ (PO₄) ₂]₂}·2H₂O (2), (H₃dien) ₄{Mn[Mo₆O₁₂(OH)₃(HPO ₄)₂(PO₄)₂]₂} ·8H₂O (3) (dien = diethylenetriamine) and (H ₂en)₅{Cu₂[Mo₆O₁₂(OH) ₃(HPO₄)₃(PO₄)]₂} ·3H₂O (4) (en = ethylenediamine) have been successfully synthesized under similar reactive condition and characterized by single-crystal X-ray diffraction. For compounds 1-3, despite slight distinction of amine, the organic amine template effect lead them to have different topological structures. The transition metal ion Mn²⁺ was replaced by Cu ⁺, resulting in compound 4 with infinite chains since Cu⁺ exhibits a two-coordination mode. To the best of our knowledge, compound 4 is the first zigzag chain-like structure reduced polyoxomolybdenum phosphates containing Cu⁺. Other characterizations of these compounds by elemental, IR, thermal analysis and catalytic properties are also performed. The formation of these four compounds reveals that the organoamine and transition metal play important roles during the synthesis.

Original language	English
Pages (from-to)	5133-5141
Number of pages	9
Journal	CrystEngComm
Volume	13
Issue number	16
DOIs	https://doi.org/10.1039/c1ce05417a
State	Published - 21 Aug 2011

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@article{34c2891b44114b5cb06b3691c41b7fb1,

title = "Effects of organoamine template and transition metal coordination mode on the self-assembly of reduced polyoxomolybdenum phosphate",

abstract = "Four new compounds of reduced polyoxomolybdenum phosphate (v) with the formula (H2enMe)4(MnH2O)2{Mn[Mo 6O12(OH)3(HPO4)2(PO 4)2]2}·5H2O (1) (enMe = 1,2-diaminopropane), (H3N(CH2)4NH 3)4(MnH2O)2{Mn[Mo6O 12(OH)3(HPO4)2 (PO4) 2]2}·2H2O (2), (H3dien) 4{Mn[Mo6O12(OH)3(HPO 4)2(PO4)2]2} ·8H2O (3) (dien = diethylenetriamine) and (H 2en)5{Cu2[Mo6O12(OH) 3(HPO4)3(PO4)]2} ·3H2O (4) (en = ethylenediamine) have been successfully synthesized under similar reactive condition and characterized by single-crystal X-ray diffraction. For compounds 1-3, despite slight distinction of amine, the organic amine template effect lead them to have different topological structures. The transition metal ion Mn2+ was replaced by Cu +, resulting in compound 4 with infinite chains since Cu+ exhibits a two-coordination mode. To the best of our knowledge, compound 4 is the first zigzag chain-like structure reduced polyoxomolybdenum phosphates containing Cu+. Other characterizations of these compounds by elemental, IR, thermal analysis and catalytic properties are also performed. The formation of these four compounds reveals that the organoamine and transition metal play important roles during the synthesis.",

author = "Dawei Yan and Jie Fu and Lei Zheng and Zhibin Zhang and Yan Xu and Xiaolei Zhu and Dunru Zhu",

year = "2011",

month = aug,

day = "21",

doi = "10.1039/c1ce05417a",

language = "英语",

volume = "13",

pages = "5133--5141",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "16",

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TY - JOUR

T1 - Effects of organoamine template and transition metal coordination mode on the self-assembly of reduced polyoxomolybdenum phosphate

AU - Yan, Dawei

AU - Fu, Jie

AU - Zheng, Lei

AU - Zhang, Zhibin

AU - Xu, Yan

AU - Zhu, Xiaolei

AU - Zhu, Dunru

PY - 2011/8/21

Y1 - 2011/8/21

N2 - Four new compounds of reduced polyoxomolybdenum phosphate (v) with the formula (H2enMe)4(MnH2O)2{Mn[Mo 6O12(OH)3(HPO4)2(PO 4)2]2}·5H2O (1) (enMe = 1,2-diaminopropane), (H3N(CH2)4NH 3)4(MnH2O)2{Mn[Mo6O 12(OH)3(HPO4)2 (PO4) 2]2}·2H2O (2), (H3dien) 4{Mn[Mo6O12(OH)3(HPO 4)2(PO4)2]2} ·8H2O (3) (dien = diethylenetriamine) and (H 2en)5{Cu2[Mo6O12(OH) 3(HPO4)3(PO4)]2} ·3H2O (4) (en = ethylenediamine) have been successfully synthesized under similar reactive condition and characterized by single-crystal X-ray diffraction. For compounds 1-3, despite slight distinction of amine, the organic amine template effect lead them to have different topological structures. The transition metal ion Mn2+ was replaced by Cu +, resulting in compound 4 with infinite chains since Cu+ exhibits a two-coordination mode. To the best of our knowledge, compound 4 is the first zigzag chain-like structure reduced polyoxomolybdenum phosphates containing Cu+. Other characterizations of these compounds by elemental, IR, thermal analysis and catalytic properties are also performed. The formation of these four compounds reveals that the organoamine and transition metal play important roles during the synthesis.

AB - Four new compounds of reduced polyoxomolybdenum phosphate (v) with the formula (H2enMe)4(MnH2O)2{Mn[Mo 6O12(OH)3(HPO4)2(PO 4)2]2}·5H2O (1) (enMe = 1,2-diaminopropane), (H3N(CH2)4NH 3)4(MnH2O)2{Mn[Mo6O 12(OH)3(HPO4)2 (PO4) 2]2}·2H2O (2), (H3dien) 4{Mn[Mo6O12(OH)3(HPO 4)2(PO4)2]2} ·8H2O (3) (dien = diethylenetriamine) and (H 2en)5{Cu2[Mo6O12(OH) 3(HPO4)3(PO4)]2} ·3H2O (4) (en = ethylenediamine) have been successfully synthesized under similar reactive condition and characterized by single-crystal X-ray diffraction. For compounds 1-3, despite slight distinction of amine, the organic amine template effect lead them to have different topological structures. The transition metal ion Mn2+ was replaced by Cu +, resulting in compound 4 with infinite chains since Cu+ exhibits a two-coordination mode. To the best of our knowledge, compound 4 is the first zigzag chain-like structure reduced polyoxomolybdenum phosphates containing Cu+. Other characterizations of these compounds by elemental, IR, thermal analysis and catalytic properties are also performed. The formation of these four compounds reveals that the organoamine and transition metal play important roles during the synthesis.

UR - http://www.scopus.com/inward/record.url?scp=79960930500&partnerID=8YFLogxK

U2 - 10.1039/c1ce05417a

DO - 10.1039/c1ce05417a

M3 - 文章

AN - SCOPUS:79960930500

SN - 1466-8033

VL - 13

SP - 5133

EP - 5141

JO - CrystEngComm

JF - CrystEngComm

IS - 16

ER -

Effects of organoamine template and transition metal coordination mode on the self-assembly of reduced polyoxomolybdenum phosphate

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