Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries

Z. H. Li; H. P. Zhang; P. Zhang; G. C. Li; Y. P. Wu; X. D. Zhou

doi:10.1016/j.memsci.2008.05.074

Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries

Z. H. Li, H. P. Zhang, P. Zhang, G. C. Li, Y. P. Wu, X. D. Zhou

Research output: Contribution to journal › Article › peer-review

114 Scopus citations

Abstract

A kind of porous nanocomposite polymer membranes (NCPMs) based on poly(vinylidene difluoride-co-hexafluoropropylene) (P(VdF-HFP)) incorporated with different amounts of TiO₂ nanoparticles from in situ hydrolysis of Ti(OC₄H₉)₄ was prepared by a non-solvent induced phase separation (NIPS) technology. The SEM micrographs reveal that a porous structure exists in the NCPMs, which changes with the incorporated amount of TiO₂. The NCPMs incorporated with 9.0 wt.% of mass fraction of TiO₂ possess the highest porosity, 67.3%, and appear as flexile fracture with an elongation ratio, 74.4%. At this content, the ionic conductivity of the NCPE is up to 0.94 × 10^-3 S cm^-1 at room temperature and the activation energy for ions transport reaches the lowest, 18.71 kJ mol^-1. It is of great potential application in lithium ion batteries.

Original language	English
Pages (from-to)	416-422
Number of pages	7
Journal	Journal of Membrane Science
Volume	322
Issue number	2
DOIs	https://doi.org/10.1016/j.memsci.2008.05.074
State	Published - 15 Sep 2008
Externally published	Yes

Keywords

In situ hydrolysis
Ionic conductivity
Lithium ion battery
Polymer electrolyte
Porous polymer membrane

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.memsci.2008.05.074

Cite this

@article{84c054c73c79477295944a670acb69ef,

title = "Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries",

abstract = "A kind of porous nanocomposite polymer membranes (NCPMs) based on poly(vinylidene difluoride-co-hexafluoropropylene) (P(VdF-HFP)) incorporated with different amounts of TiO2 nanoparticles from in situ hydrolysis of Ti(OC4H9)4 was prepared by a non-solvent induced phase separation (NIPS) technology. The SEM micrographs reveal that a porous structure exists in the NCPMs, which changes with the incorporated amount of TiO2. The NCPMs incorporated with 9.0 wt.% of mass fraction of TiO2 possess the highest porosity, 67.3%, and appear as flexile fracture with an elongation ratio, 74.4%. At this content, the ionic conductivity of the NCPE is up to 0.94 × 10-3 S cm-1 at room temperature and the activation energy for ions transport reaches the lowest, 18.71 kJ mol-1. It is of great potential application in lithium ion batteries.",

keywords = "In situ hydrolysis, Ionic conductivity, Lithium ion battery, Polymer electrolyte, Porous polymer membrane",

author = "Li, {Z. H.} and Zhang, {H. P.} and P. Zhang and Li, {G. C.} and Wu, {Y. P.} and Zhou, {X. D.}",

year = "2008",

month = sep,

day = "15",

doi = "10.1016/j.memsci.2008.05.074",

language = "英语",

volume = "322",

pages = "416--422",

journal = "Journal of Membrane Science",

issn = "0376-7388",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries

AU - Li, Z. H.

AU - Zhang, H. P.

AU - Zhang, P.

AU - Li, G. C.

AU - Wu, Y. P.

AU - Zhou, X. D.

PY - 2008/9/15

Y1 - 2008/9/15

N2 - A kind of porous nanocomposite polymer membranes (NCPMs) based on poly(vinylidene difluoride-co-hexafluoropropylene) (P(VdF-HFP)) incorporated with different amounts of TiO2 nanoparticles from in situ hydrolysis of Ti(OC4H9)4 was prepared by a non-solvent induced phase separation (NIPS) technology. The SEM micrographs reveal that a porous structure exists in the NCPMs, which changes with the incorporated amount of TiO2. The NCPMs incorporated with 9.0 wt.% of mass fraction of TiO2 possess the highest porosity, 67.3%, and appear as flexile fracture with an elongation ratio, 74.4%. At this content, the ionic conductivity of the NCPE is up to 0.94 × 10-3 S cm-1 at room temperature and the activation energy for ions transport reaches the lowest, 18.71 kJ mol-1. It is of great potential application in lithium ion batteries.

AB - A kind of porous nanocomposite polymer membranes (NCPMs) based on poly(vinylidene difluoride-co-hexafluoropropylene) (P(VdF-HFP)) incorporated with different amounts of TiO2 nanoparticles from in situ hydrolysis of Ti(OC4H9)4 was prepared by a non-solvent induced phase separation (NIPS) technology. The SEM micrographs reveal that a porous structure exists in the NCPMs, which changes with the incorporated amount of TiO2. The NCPMs incorporated with 9.0 wt.% of mass fraction of TiO2 possess the highest porosity, 67.3%, and appear as flexile fracture with an elongation ratio, 74.4%. At this content, the ionic conductivity of the NCPE is up to 0.94 × 10-3 S cm-1 at room temperature and the activation energy for ions transport reaches the lowest, 18.71 kJ mol-1. It is of great potential application in lithium ion batteries.

KW - In situ hydrolysis

KW - Ionic conductivity

KW - Lithium ion battery

KW - Polymer electrolyte

KW - Porous polymer membrane

UR - http://www.scopus.com/inward/record.url?scp=48149087061&partnerID=8YFLogxK

U2 - 10.1016/j.memsci.2008.05.074

DO - 10.1016/j.memsci.2008.05.074

M3 - 文章

AN - SCOPUS:48149087061

SN - 0376-7388

VL - 322

SP - 416

EP - 422

JO - Journal of Membrane Science

JF - Journal of Membrane Science

IS - 2

ER -

Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries

Abstract

Keywords

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this