Engineering channels of metal-organic frameworks to enhance catalytic selectivity

Ye Liu; Yu Shen; Weina Zhang; Jiena Weng; Meiting Zhao; Tingshun Zhu; Yonggui Robin Chi; Yanhui Yang; Hua Zhang; Fengwei Huo

doi:10.1039/c9cc06061h

Engineering channels of metal-organic frameworks to enhance catalytic selectivity

Ye Liu, Yu Shen, Weina Zhang, Jiena Weng, Meiting Zhao, Tingshun Zhu, Yonggui Robin Chi, Yanhui Yang, Hua Zhang, Fengwei Huo

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.

Original language	English
Pages (from-to)	11770-11773
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	78
DOIs	https://doi.org/10.1039/c9cc06061h
State	Published - 2019

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title = "Engineering channels of metal-organic frameworks to enhance catalytic selectivity",

abstract = "This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.",

author = "Ye Liu and Yu Shen and Weina Zhang and Jiena Weng and Meiting Zhao and Tingshun Zhu and Chi, {Yonggui Robin} and Yanhui Yang and Hua Zhang and Fengwei Huo",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc06061h",

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volume = "55",

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TY - JOUR

T1 - Engineering channels of metal-organic frameworks to enhance catalytic selectivity

AU - Liu, Ye

AU - Shen, Yu

AU - Zhang, Weina

AU - Weng, Jiena

AU - Zhao, Meiting

AU - Zhu, Tingshun

AU - Chi, Yonggui Robin

AU - Yang, Yanhui

AU - Zhang, Hua

AU - Huo, Fengwei

PY - 2019

Y1 - 2019

N2 - This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.

AB - This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.

UR - http://www.scopus.com/inward/record.url?scp=85072686923&partnerID=8YFLogxK

U2 - 10.1039/c9cc06061h

DO - 10.1039/c9cc06061h

M3 - 文章

C2 - 31513185

AN - SCOPUS:85072686923

SN - 1359-7345

VL - 55

SP - 11770

EP - 11773

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

Engineering channels of metal-organic frameworks to enhance catalytic selectivity

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