Experimental and theoretical analysis on the thermomechanical properties of functionally graded graphene nanoplatelet reinforced cement composites

Graphene reinforced cement composites (GRCCs) have attracted great attention due to their excellent mechanical and physical properties. Instead of uniform distribution, the functionally graded distribution of graphene fillers can effectively utilize the mechanical and physical properties of the reinforcements while reducing cost. This paper is the first attempt to combine experimental analysis and theoretical modelling to investigate the thermomechanical properties of functionally graded graphene nanoplatelet (GNP) reinforced cement composites (FG-GNPRCCs). Samples with uniform (profile H) and functionally graded (profiles X, O and A) distribution of GNPs were prepared and tested. Among all the FG distribution patterns as involved, profile X exhibited the most pronounced enhancement. Compared to the uniform distribution at room temperature, the loss factor and storage modulus of profile X increased by 19.3 % and 19.5 %, respectively. Based on the effective medium theory (EMT) and Mori-Tanaka (MT) model, a parallel triple-inclusion model was developed to predict the thermal conductivity of GNPRCCs. The effects of coated GNP, agglomeration and the attributes of pores (i.e., size, shape and porosity) on the thermomechanical properties of the composites were considered. Dynamic mechanical analysis revealed that profile X had the best energy dissipation and the extent of inelastic deformation within the temperature range from −50 °C to 70 °C. In contrast, profile A is beneficial for scenarios that desire a gradual transition and controlled stress along a certain direction.