Facile synthesis of porous organic polymers bifunctionalized with azo and porphyrin groups

Xiaowei Jiang; Yunfei Liu; Jun Liu; Yali Luo; Yinong Lyu

doi:10.1039/c5ra19422a

Facile synthesis of porous organic polymers bifunctionalized with azo and porphyrin groups

Xiaowei Jiang, Yunfei Liu, Jun Liu, Yali Luo, Yinong Lyu

College of Materials Science and Engineering

Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Azo and porphyrin bifunctionalized porous polymers networks (azo-PPors) were synthesized via a catalyst-free direct coupling of tetra(4-nitrophenyl)porphyrin and several readily available aryl amine monomers. The resulting porous solids exhibited surface areas up to 750 m² g^-1, with high thermal and chemical stability. Owing to the high concentration of Lewis basic N-sites at their surfaces (derived from porphyrin rings and azo units), these azo-PPors have high CO₂ capture (up to 2.45 mmol g^-1) and good selectivity for CO₂/CH₄ adsorption (5) at 273 K/1.0 bar, thus showing good potential for CO₂ capture.

Original language	English
Pages (from-to)	98508-98513
Number of pages	6
Journal	RSC Advances
Volume	5
Issue number	119
DOIs	https://doi.org/10.1039/c5ra19422a
State	Published - 2015

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title = "Facile synthesis of porous organic polymers bifunctionalized with azo and porphyrin groups",

abstract = "Azo and porphyrin bifunctionalized porous polymers networks (azo-PPors) were synthesized via a catalyst-free direct coupling of tetra(4-nitrophenyl)porphyrin and several readily available aryl amine monomers. The resulting porous solids exhibited surface areas up to 750 m2 g-1, with high thermal and chemical stability. Owing to the high concentration of Lewis basic N-sites at their surfaces (derived from porphyrin rings and azo units), these azo-PPors have high CO2 capture (up to 2.45 mmol g-1) and good selectivity for CO2/CH4 adsorption (5) at 273 K/1.0 bar, thus showing good potential for CO2 capture.",

author = "Xiaowei Jiang and Yunfei Liu and Jun Liu and Yali Luo and Yinong Lyu",

note = "Publisher Copyright: {\textcopyright} 2015 The Royal Society of Chemistry.",

year = "2015",

doi = "10.1039/c5ra19422a",

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T1 - Facile synthesis of porous organic polymers bifunctionalized with azo and porphyrin groups

AU - Jiang, Xiaowei

AU - Liu, Yunfei

AU - Liu, Jun

AU - Luo, Yali

AU - Lyu, Yinong

PY - 2015

Y1 - 2015

N2 - Azo and porphyrin bifunctionalized porous polymers networks (azo-PPors) were synthesized via a catalyst-free direct coupling of tetra(4-nitrophenyl)porphyrin and several readily available aryl amine monomers. The resulting porous solids exhibited surface areas up to 750 m2 g-1, with high thermal and chemical stability. Owing to the high concentration of Lewis basic N-sites at their surfaces (derived from porphyrin rings and azo units), these azo-PPors have high CO2 capture (up to 2.45 mmol g-1) and good selectivity for CO2/CH4 adsorption (5) at 273 K/1.0 bar, thus showing good potential for CO2 capture.

AB - Azo and porphyrin bifunctionalized porous polymers networks (azo-PPors) were synthesized via a catalyst-free direct coupling of tetra(4-nitrophenyl)porphyrin and several readily available aryl amine monomers. The resulting porous solids exhibited surface areas up to 750 m2 g-1, with high thermal and chemical stability. Owing to the high concentration of Lewis basic N-sites at their surfaces (derived from porphyrin rings and azo units), these azo-PPors have high CO2 capture (up to 2.45 mmol g-1) and good selectivity for CO2/CH4 adsorption (5) at 273 K/1.0 bar, thus showing good potential for CO2 capture.

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U2 - 10.1039/c5ra19422a

DO - 10.1039/c5ra19422a

M3 - 文章

AN - SCOPUS:84948451833

SN - 2046-2069

VL - 5

SP - 98508

EP - 98513

JO - RSC Advances

JF - RSC Advances

IS - 119

ER -

Facile synthesis of porous organic polymers bifunctionalized with azo and porphyrin groups

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