Fly ash derived calcium silicate hydrate as a highly efficient and fast adsorbent for Cu(ii) ions: role of copolymer functionalization

The environmental issues caused by heavy metal accumulation from polluted water are becoming serious and threaten human health and the ecosystem. The adsorption technology represented by calcium silicate hydrate has attracted much attention, but suffers from high manufacturing costs and poor stability bottlenecks. Here, we have proposed a “trash-to-treasure” conversion strategy to prepare a thin sheet calcium silicate hydrate material (ACSH) using solid waste fly ash as silicon source and a small amount of Acumer2000 as modifier. The obtained materials showed fast adsorption rates, superior adsorption capacities and remarkable long-term stability for Cu(ii) removal. Under the conditions of 0.5 g L⁻¹ adsorbent concentration and 100 mL Cu(ii) solution with a concentration of 100 mg L⁻¹, ACSH can adsorb 95.6% Cu(ii) within 5 min. The adsorption isotherms conformed to Langmuir models and the maximum adsorption capacity was 532 mg g⁻¹. Using X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, specific surface area and pore structure analysis, it was found that the excellent adsorption performance could be attributed to the ultrahigh surface area (356 m² g⁻¹), abundant pores and multiple active sites induced by Acumer2000 modification. Moreover, the encapsulation effect from carboxylate and long carbon chains in Acumer2000 endowed modified samples with strong corrosion resistance to CO₂, which effectively inhibited the formation of by-product CaCO₃ and retained the remarkable adsorption performance for more than 100 days. Interestingly enough, the advantages of ACSH in economy and performance could been maintained in ACSH based adsorptive membranes. This work is of great significance for solid waste utilization as well as the preparation of high quality, cost-effective and long-term stability calcium silicate hydrate materials.