Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)2]−

Qingnan Zhang; Wan Lu Li; Cong Qiao Xu; Mohua Chen; Mingfei Zhou; Jun Li; Diego M. Andrada; Gernot Frenking

doi:10.1002/anie.201503686

Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)₂]⁻

Qingnan Zhang, Wan Lu Li, Cong Qiao Xu, Mohua Chen, Mingfei Zhou, Jun Li, Diego M. Andrada, Gernot Frenking

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)₂]⁻. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)₂]⁻using state-of-the-art quantum chemical methods.

Original language	English
Pages (from-to)	11078-11083
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	54
Issue number	38
DOIs	https://doi.org/10.1002/anie.201503686
State	Published - 14 Sep 2015
Externally published	Yes

Keywords

bonding analysis
boron dicarbonyl compound
matrix isolation
quantum chemical calculations

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10.1002/anie.201503686

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abstract = "We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2]−. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2]−using state-of-the-art quantum chemical methods.",

keywords = "bonding analysis, boron dicarbonyl compound, matrix isolation, quantum chemical calculations",

author = "Qingnan Zhang and Li, {Wan Lu} and Xu, {Cong Qiao} and Mohua Chen and Mingfei Zhou and Jun Li and Andrada, {Diego M.} and Gernot Frenking",

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AU - Zhang, Qingnan

AU - Li, Wan Lu

AU - Xu, Cong Qiao

AU - Chen, Mohua

AU - Zhou, Mingfei

AU - Li, Jun

AU - Andrada, Diego M.

AU - Frenking, Gernot

PY - 2015/9/14

Y1 - 2015/9/14

N2 - We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2]−. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2]−using state-of-the-art quantum chemical methods.

AB - We report the synthesis and spectroscopic characterization of the boron dicarbonyl complex [B(CO)2]−. The bonding situation is analyzed and compared with the aluminum homologue [Al(CO)2]−using state-of-the-art quantum chemical methods.

KW - bonding analysis

KW - boron dicarbonyl compound

KW - matrix isolation

KW - quantum chemical calculations

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M3 - 文章

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JO - Angewandte Chemie - International Edition

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ER -

Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)₂]⁻

Abstract

Keywords

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