Fusing high symmetric coordination polyhedrons of Cu6(PIP) 4, Cu12(PIP)8, and Cu12(PIP) 24 into an unprecedented porous MOF: Synthesis, structure, and its remarkable CO2 selectivity

Ruirui Yun; Jingui Duan; Junfeng Bai; Yizhi Li

doi:10.1021/cg301577a

Fusing high symmetric coordination polyhedrons of Cu₆(PIP) ₄, Cu₁₂(PIP)₈, and Cu₁₂(PIP) ₂₄ into an unprecedented porous MOF: Synthesis, structure, and its remarkable CO₂ selectivity

Ruirui Yun, Jingui Duan, Junfeng Bai, Yizhi Li

Nanjing University

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

An unprecedented metal-organic framework, NJU-Bai6, formed by piling up the nanocages Cu₆(PIP)₄, Cu₁₂(PIP)₈, and Cu₁₂(PIP)₂₄ through sharing faces of the "opened" triangular and square windows, has been designed and structurally characterized. Very interestingly, it exhibits the third highest selectivity of CO₂ over N₂ with the value about 60 at room temperature.

Original language	English
Pages (from-to)	24-26
Number of pages	3
Journal	Crystal Growth and Design
Volume	13
Issue number	1
DOIs	https://doi.org/10.1021/cg301577a
State	Published - 2 Jan 2013
Externally published	Yes

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abstract = "An unprecedented metal-organic framework, NJU-Bai6, formed by piling up the nanocages Cu6(PIP)4, Cu12(PIP)8, and Cu12(PIP)24 through sharing faces of the {"}opened{"} triangular and square windows, has been designed and structurally characterized. Very interestingly, it exhibits the third highest selectivity of CO2 over N2 with the value about 60 at room temperature.",

author = "Ruirui Yun and Jingui Duan and Junfeng Bai and Yizhi Li",

year = "2013",

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T2 - Synthesis, structure, and its remarkable CO2 selectivity

AU - Yun, Ruirui

AU - Duan, Jingui

AU - Bai, Junfeng

AU - Li, Yizhi

PY - 2013/1/2

Y1 - 2013/1/2

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AB - An unprecedented metal-organic framework, NJU-Bai6, formed by piling up the nanocages Cu6(PIP)4, Cu12(PIP)8, and Cu12(PIP)24 through sharing faces of the "opened" triangular and square windows, has been designed and structurally characterized. Very interestingly, it exhibits the third highest selectivity of CO2 over N2 with the value about 60 at room temperature.

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DO - 10.1021/cg301577a

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Fusing high symmetric coordination polyhedrons of Cu₆(PIP) ₄, Cu₁₂(PIP)₈, and Cu₁₂(PIP) ₂₄ into an unprecedented porous MOF: Synthesis, structure, and its remarkable CO₂ selectivity

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