[Ga@Bi10(NbMes)2]3−: a linear Nb-GaI-Nb filament coordinated by a bismuth cage

Lei Qiao; Tao Yang; Gernot Frenking; Zhong Ming Sun

doi:10.1039/d3cc00631j

[Ga@Bi₁₀(NbMes)₂]³⁻: a linear Nb-Ga^I-Nb filament coordinated by a bismuth cage

Lei Qiao, Tao Yang, Gernot Frenking, Zhong Ming Sun

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

In this work, we report a low-valent Ga(i) complex, [Ga@Bi₁₀(NbMes)₂]³⁻, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.

Original language	English
Pages (from-to)	4024-4027
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	27
DOIs	https://doi.org/10.1039/d3cc00631j
State	Published - 8 Mar 2023
Externally published	Yes

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10.1039/d3cc00631j

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title = "[Ga@Bi10(NbMes)2]3−: a linear Nb-GaI-Nb filament coordinated by a bismuth cage",

abstract = "In this work, we report a low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.",

author = "Lei Qiao and Tao Yang and Gernot Frenking and Sun, {Zhong Ming}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

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TY - JOUR

T1 - [Ga@Bi10(NbMes)2]3−

T2 - a linear Nb-GaI-Nb filament coordinated by a bismuth cage

AU - Qiao, Lei

AU - Yang, Tao

AU - Frenking, Gernot

AU - Sun, Zhong Ming

PY - 2023/3/8

Y1 - 2023/3/8

N2 - In this work, we report a low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.

AB - In this work, we report a low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb-Ga-Nb fragment, representing the first compound with Nb-Ga and Nb-Bi bonds. Quantum-chemical calculations reveal that the complex is an electron-precise cluster. The possible fragmentation pathway of the title cluster was studied by using electrospray ionization mass spectrometry and theoretical calculations.

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U2 - 10.1039/d3cc00631j

DO - 10.1039/d3cc00631j

M3 - 文章

C2 - 36920786

AN - SCOPUS:85150897718

SN - 1359-7345

VL - 59

SP - 4024

EP - 4027

JO - Chemical Communications

JF - Chemical Communications

IS - 27

ER -

[Ga@Bi₁₀(NbMes)₂]³⁻: a linear Nb-Ga^I-Nb filament coordinated by a bismuth cage

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