Geometrical effect of CuO nanostructures on catalytic benzene combustion

Zhaoyang Fei; Ping Lu; Xinzhen Feng; Bo Sun; Weijie Ji

doi:10.1039/c2cy20168b

Geometrical effect of CuO nanostructures on catalytic benzene combustion

Zhaoyang Fei, Ping Lu, Xinzhen Feng, Bo Sun, Weijie Ji

Nanjing University

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

CuO nanostructures of different morphologies were synthesized and compared for catalytic benzene combustion. XRD patterns of various CuO nano-crystallites suggest the monoclinic CuO structure. The dominant crystal planes of various CuO nanostructures are identified by means of HRTEM and electron diffraction. The amount of oxygen adspecies was found to be strongly dependent on the orientation of crystal planes. The activity of benzene combustion over major crystal planes of CuO nanostructures is: (200) > (111) > (011) > (001), consistent with the order of the corresponding density of terminate Cu ²⁺ ions on which both benzene and oxygen are activated.

Original language	English
Pages (from-to)	1705-1710
Number of pages	6
Journal	Catalysis Science and Technology
Volume	2
Issue number	8
DOIs	https://doi.org/10.1039/c2cy20168b
State	Published - Aug 2012
Externally published	Yes

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title = "Geometrical effect of CuO nanostructures on catalytic benzene combustion",

abstract = "CuO nanostructures of different morphologies were synthesized and compared for catalytic benzene combustion. XRD patterns of various CuO nano-crystallites suggest the monoclinic CuO structure. The dominant crystal planes of various CuO nanostructures are identified by means of HRTEM and electron diffraction. The amount of oxygen adspecies was found to be strongly dependent on the orientation of crystal planes. The activity of benzene combustion over major crystal planes of CuO nanostructures is: (200) > (111) > (011) > (001), consistent with the order of the corresponding density of terminate Cu 2+ ions on which both benzene and oxygen are activated.",

author = "Zhaoyang Fei and Ping Lu and Xinzhen Feng and Bo Sun and Weijie Ji",

year = "2012",

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AU - Fei, Zhaoyang

AU - Lu, Ping

AU - Feng, Xinzhen

AU - Sun, Bo

AU - Ji, Weijie

PY - 2012/8

Y1 - 2012/8

N2 - CuO nanostructures of different morphologies were synthesized and compared for catalytic benzene combustion. XRD patterns of various CuO nano-crystallites suggest the monoclinic CuO structure. The dominant crystal planes of various CuO nanostructures are identified by means of HRTEM and electron diffraction. The amount of oxygen adspecies was found to be strongly dependent on the orientation of crystal planes. The activity of benzene combustion over major crystal planes of CuO nanostructures is: (200) > (111) > (011) > (001), consistent with the order of the corresponding density of terminate Cu 2+ ions on which both benzene and oxygen are activated.

AB - CuO nanostructures of different morphologies were synthesized and compared for catalytic benzene combustion. XRD patterns of various CuO nano-crystallites suggest the monoclinic CuO structure. The dominant crystal planes of various CuO nanostructures are identified by means of HRTEM and electron diffraction. The amount of oxygen adspecies was found to be strongly dependent on the orientation of crystal planes. The activity of benzene combustion over major crystal planes of CuO nanostructures is: (200) > (111) > (011) > (001), consistent with the order of the corresponding density of terminate Cu 2+ ions on which both benzene and oxygen are activated.

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JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

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Geometrical effect of CuO nanostructures on catalytic benzene combustion

Abstract

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