Hoveyda-Grubbs II Catalyst: A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions

Yun Ge; Wangbin Sun; Bingbing Pei; Jia Ding; Yaojia Jiang; Teck Peng Loh

doi:10.1021/acs.orglett.8b00971

Hoveyda-Grubbs II Catalyst: A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions

Yun Ge, Wangbin Sun, Bingbing Pei, Jia Ding, Yaojia Jiang, Teck Peng Loh

School of Chemistry and Moleculai Engineering

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A one-pot reaction to synthesize functionalized 2H-azirines through visible-light-mediated ring contraction and olefin metathesis of isoxazoles is described. Hoveyda-Grubbs II catalyst was found to function as a photocatalyst for these transformations, allowing these processes to be carried out in a one-pot manner. This study offers a new entry for the application of Grubbs catalysts as efficient photocatalysts and the possibilities of carrying out other photoreactions and olefin metathesis in a one-pot process.

Original language	English
Pages (from-to)	2774-2777
Number of pages	4
Journal	Organic Letters
Volume	20
Issue number	9
DOIs	https://doi.org/10.1021/acs.orglett.8b00971
State	Published - 4 May 2018

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title = "Hoveyda-Grubbs II Catalyst: A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions",

abstract = "A one-pot reaction to synthesize functionalized 2H-azirines through visible-light-mediated ring contraction and olefin metathesis of isoxazoles is described. Hoveyda-Grubbs II catalyst was found to function as a photocatalyst for these transformations, allowing these processes to be carried out in a one-pot manner. This study offers a new entry for the application of Grubbs catalysts as efficient photocatalysts and the possibilities of carrying out other photoreactions and olefin metathesis in a one-pot process.",

author = "Yun Ge and Wangbin Sun and Bingbing Pei and Jia Ding and Yaojia Jiang and Loh, {Teck Peng}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = may,

day = "4",

doi = "10.1021/acs.orglett.8b00971",

language = "英语",

volume = "20",

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T1 - Hoveyda-Grubbs II Catalyst

T2 - A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions

AU - Ge, Yun

AU - Sun, Wangbin

AU - Pei, Bingbing

AU - Ding, Jia

AU - Jiang, Yaojia

AU - Loh, Teck Peng

PY - 2018/5/4

Y1 - 2018/5/4

N2 - A one-pot reaction to synthesize functionalized 2H-azirines through visible-light-mediated ring contraction and olefin metathesis of isoxazoles is described. Hoveyda-Grubbs II catalyst was found to function as a photocatalyst for these transformations, allowing these processes to be carried out in a one-pot manner. This study offers a new entry for the application of Grubbs catalysts as efficient photocatalysts and the possibilities of carrying out other photoreactions and olefin metathesis in a one-pot process.

AB - A one-pot reaction to synthesize functionalized 2H-azirines through visible-light-mediated ring contraction and olefin metathesis of isoxazoles is described. Hoveyda-Grubbs II catalyst was found to function as a photocatalyst for these transformations, allowing these processes to be carried out in a one-pot manner. This study offers a new entry for the application of Grubbs catalysts as efficient photocatalysts and the possibilities of carrying out other photoreactions and olefin metathesis in a one-pot process.

UR - http://www.scopus.com/inward/record.url?scp=85046643010&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.8b00971

DO - 10.1021/acs.orglett.8b00971

M3 - 文章

C2 - 29693396

AN - SCOPUS:85046643010

SN - 1523-7060

VL - 20

SP - 2774

EP - 2777

JO - Organic Letters

JF - Organic Letters

IS - 9

ER -

Hoveyda-Grubbs II Catalyst: A Useful Catalyst for One-Pot Visible-Light-Promoted Ring Contraction and Olefin Metathesis Reactions

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