Hydrothermal Syntheses and Crystal Structures of Two New Vanadium Phosphates

Zhibin Zhang; Jiuyu Guo; Jie Fu; Lei Zheng; Dunru Zhu; Yan Xu; You Song

doi:10.1007/s10876-011-0385-3

Hydrothermal Syntheses and Crystal Structures of Two New Vanadium Phosphates

Zhibin Zhang, Jiuyu Guo, Jie Fu, Lei Zheng, Dunru Zhu, Yan Xu, You Song

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Two new vanadium phosphates (NH ₄) ₅[C ₄N ₃H ₁₆] ₂[NH ₃(CH ₂) ₂NH ₃] ₂[PV ₁₈ ^IVO ₄₆]·H ₂O (1) and [C ₄N ₃H ₁₆] ₄[(PV ₁₂ ^IVV ₆ ^VO ₄₆)(PO ₄)]·H ₂O (2) have been successfully synthesized under hydrothermal conditions and structurally characterized by elemental analysis, infrared (IR), thermogravimetry (TG), and single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P21/n, a = 13.183(8), b = 20.148(13), c = 22.273(14) Å, β = 102.198(8)°, V = 5,782(6) Å ³, Z = 4; compound 2 crystallizes in the monoclinic system, space group C2/c, a = 23.917(2), b = 12.9647(12), c = 20.1922(19) Å, β = 105.382(1)°, V = 6,036. 9(10) Å ³, Z = 4. Magnetic susceptibility measurements reveal antiferromagnetic interactions between V ⁴⁺ atoms of 1 and 2.

Original language	English
Pages (from-to)	177-187
Number of pages	11
Journal	Journal of Cluster Science
Volume	23
Issue number	2
DOIs	https://doi.org/10.1007/s10876-011-0385-3
State	Published - Jun 2012

Keywords

Crystal structure
Discrete
Hydrothermal synthesis
Vanadium phosphate

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@article{40ef299ede484619919ffa9d96a54048,

title = "Hydrothermal Syntheses and Crystal Structures of Two New Vanadium Phosphates",

abstract = "Two new vanadium phosphates (NH 4) 5[C 4N 3H 16] 2[NH 3(CH 2) 2NH 3] 2[PV 18 IVO 46]·H 2O (1) and [C 4N 3H 16] 4[(PV 12 IVV 6 VO 46)(PO 4)]·H 2O (2) have been successfully synthesized under hydrothermal conditions and structurally characterized by elemental analysis, infrared (IR), thermogravimetry (TG), and single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P21/n, a = 13.183(8), b = 20.148(13), c = 22.273(14) {\AA}, β = 102.198(8)°, V = 5,782(6) {\AA} 3, Z = 4; compound 2 crystallizes in the monoclinic system, space group C2/c, a = 23.917(2), b = 12.9647(12), c = 20.1922(19) {\AA}, β = 105.382(1)°, V = 6,036. 9(10) {\AA} 3, Z = 4. Magnetic susceptibility measurements reveal antiferromagnetic interactions between V 4+ atoms of 1 and 2.",

keywords = "Crystal structure, Discrete, Hydrothermal synthesis, Vanadium phosphate",

author = "Zhibin Zhang and Jiuyu Guo and Jie Fu and Lei Zheng and Dunru Zhu and Yan Xu and You Song",

year = "2012",

month = jun,

doi = "10.1007/s10876-011-0385-3",

language = "英语",

volume = "23",

pages = "177--187",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "2",

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TY - JOUR

T1 - Hydrothermal Syntheses and Crystal Structures of Two New Vanadium Phosphates

AU - Zhang, Zhibin

AU - Guo, Jiuyu

AU - Fu, Jie

AU - Zheng, Lei

AU - Zhu, Dunru

AU - Xu, Yan

AU - Song, You

PY - 2012/6

Y1 - 2012/6

N2 - Two new vanadium phosphates (NH 4) 5[C 4N 3H 16] 2[NH 3(CH 2) 2NH 3] 2[PV 18 IVO 46]·H 2O (1) and [C 4N 3H 16] 4[(PV 12 IVV 6 VO 46)(PO 4)]·H 2O (2) have been successfully synthesized under hydrothermal conditions and structurally characterized by elemental analysis, infrared (IR), thermogravimetry (TG), and single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P21/n, a = 13.183(8), b = 20.148(13), c = 22.273(14) Å, β = 102.198(8)°, V = 5,782(6) Å 3, Z = 4; compound 2 crystallizes in the monoclinic system, space group C2/c, a = 23.917(2), b = 12.9647(12), c = 20.1922(19) Å, β = 105.382(1)°, V = 6,036. 9(10) Å 3, Z = 4. Magnetic susceptibility measurements reveal antiferromagnetic interactions between V 4+ atoms of 1 and 2.

AB - Two new vanadium phosphates (NH 4) 5[C 4N 3H 16] 2[NH 3(CH 2) 2NH 3] 2[PV 18 IVO 46]·H 2O (1) and [C 4N 3H 16] 4[(PV 12 IVV 6 VO 46)(PO 4)]·H 2O (2) have been successfully synthesized under hydrothermal conditions and structurally characterized by elemental analysis, infrared (IR), thermogravimetry (TG), and single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P21/n, a = 13.183(8), b = 20.148(13), c = 22.273(14) Å, β = 102.198(8)°, V = 5,782(6) Å 3, Z = 4; compound 2 crystallizes in the monoclinic system, space group C2/c, a = 23.917(2), b = 12.9647(12), c = 20.1922(19) Å, β = 105.382(1)°, V = 6,036. 9(10) Å 3, Z = 4. Magnetic susceptibility measurements reveal antiferromagnetic interactions between V 4+ atoms of 1 and 2.

KW - Crystal structure

KW - Discrete

KW - Hydrothermal synthesis

KW - Vanadium phosphate

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DO - 10.1007/s10876-011-0385-3

M3 - 文章

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JO - Journal of Cluster Science

JF - Journal of Cluster Science

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ER -

Hydrothermal Syntheses and Crystal Structures of Two New Vanadium Phosphates

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