Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La 3(SO4)6(H2O)3] constructed from La-O-S tubes and cubic cages

Lei Zheng; Zhibin Zhang; Dunru Zhu; Yan Xu

doi:10.1016/j.inoche.2010.11.008

Hydrothermal synthesis and characterization of a Na⁺ templated new 3-D lanthanum sulfate Na[C₆H₁₄N₂][La ₃(SO₄)₆(H₂O)₃] constructed from La-O-S tubes and cubic cages

Lei Zheng, Zhibin Zhang, Dunru Zhu, Yan Xu

College of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A new lanthanum sulfate Na[C₆H₁₄N₂] [La₃(SO₄)₆(H₂O)₃] 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR and TGA. Structure analysis indicates that the structure of 1 features unusual three-dimensional inorganic framework constructed from La-O-S tubes and cubic cages. The Na⁺ plays an important role in the formation of 3-D open framework of 1.

Original language	English
Pages (from-to)	258-260
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2010.11.008
State	Published - Jan 2011

Keywords

3D framework
Crystal structures
Hydrothermal synthesis
Lanthanum sulfates
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10.1016/j.inoche.2010.11.008

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title = "Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La 3(SO4)6(H2O)3] constructed from La-O-S tubes and cubic cages",

abstract = "A new lanthanum sulfate Na[C6H14N2] [La3(SO4)6(H2O)3] 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR and TGA. Structure analysis indicates that the structure of 1 features unusual three-dimensional inorganic framework constructed from La-O-S tubes and cubic cages. The Na+ plays an important role in the formation of 3-D open framework of 1.",

keywords = "3D framework, Crystal structures, Hydrothermal synthesis, Lanthanum sulfates, Template",

author = "Lei Zheng and Zhibin Zhang and Dunru Zhu and Yan Xu",

year = "2011",

month = jan,

doi = "10.1016/j.inoche.2010.11.008",

language = "英语",

volume = "14",

pages = "258--260",

journal = "Inorganic Chemistry Communications",

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T1 - Hydrothermal synthesis and characterization of a Na+ templated new 3-D lanthanum sulfate Na[C6H14N2][La 3(SO4)6(H2O)3] constructed from La-O-S tubes and cubic cages

AU - Zheng, Lei

AU - Zhang, Zhibin

AU - Zhu, Dunru

AU - Xu, Yan

PY - 2011/1

Y1 - 2011/1

N2 - A new lanthanum sulfate Na[C6H14N2] [La3(SO4)6(H2O)3] 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR and TGA. Structure analysis indicates that the structure of 1 features unusual three-dimensional inorganic framework constructed from La-O-S tubes and cubic cages. The Na+ plays an important role in the formation of 3-D open framework of 1.

AB - A new lanthanum sulfate Na[C6H14N2] [La3(SO4)6(H2O)3] 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR and TGA. Structure analysis indicates that the structure of 1 features unusual three-dimensional inorganic framework constructed from La-O-S tubes and cubic cages. The Na+ plays an important role in the formation of 3-D open framework of 1.

KW - 3D framework

KW - Crystal structures

KW - Hydrothermal synthesis

KW - Lanthanum sulfates

KW - Template

UR - http://www.scopus.com/inward/record.url?scp=78651277866&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2010.11.008

DO - 10.1016/j.inoche.2010.11.008

M3 - 文章

AN - SCOPUS:78651277866

SN - 1387-7003

VL - 14

SP - 258

EP - 260

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

Hydrothermal synthesis and characterization of a Na⁺ templated new 3-D lanthanum sulfate Na[C₆H₁₄N₂][La ₃(SO₄)₆(H₂O)₃] constructed from La-O-S tubes and cubic cages

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